ArticleNature chemistry2016
Oligomeric ferrocene rings.
Article in Nature chemistry, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- The Missing Link in Ferrocenophane Chemistry: Isolation of a Carba[1]Ferrocenophane.Angewandte Chemie (International ed. in English) · 2026Article
- Article
- Coexistence of Metallocene Cations and Anions.Journal of the American Chemical Society · 2025Article
- Intervalence Charge Transfer in an Osmium(IV) Tetra(ferrocenylaryl) Complex.Inorganic chemistry · 2025Article
- Side-Chain Type Ferrocene Macrocycles.Precision chemistry · 2024Article
- Doping Ferrocene-Based Conjugated Microporous Polymers with 7,7,8,8-Tetracyanoquinodimethane for Efficient Photocatalytic COMolecules (Basel, Switzerland) · 2024Article
- Article
- Advances of Various Heterogeneous Structure Types in Molecular Junction Systems and Their Charge Transport Properties.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022Review
- Oxidation triggers guest dissociation during reorganization of an FeChemical science · 2020Article
- Triple the fun: tris(ferrocenyl)arene-based gold(i) complexes for redox-switchable catalysis.Chemical science · 2020Article
- Fulvalene as a platform for the synthesis of a dimetallic dysprosocenium single-molecule magnet.Chemical science · 2020Article
- Article
- Ferrocene- and Biferrocene-Containing Macrocycles towards Single-Molecule Electronics.Angewandte Chemie (International ed. in English) · 2017Article
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Cyclic oligomers comprising strongly interacting redox-active monomer units represent an unknown, yet highly desirable class of nanoscale materials. Here we describe the synthesis and properties of the first family of molecules belonging to this compound category-differently sized rings comprising only 1,1'-disubstituted ferrocene units (cyclo[n], n = 5-7, 9). Due to the close proximity and connectivity of centres (covalent Cp-Cp linkages; Cp = cyclopentadienyl) solution voltammograms exhibit well-resolved, separated 1e(-) waves. Theoretical interrogations into correlations based on ring size and charge state are facilitated using values of the equilibrium potentials of these transitions, as well as their relative spacing. As the interaction free energies between the redox centres scale linearly with overall ring charge and in conjunction with fast intramolecular electron transfer (∼10(7) s(-1)), these molecules can be considered as uniformly charged nanorings (diameter ∼1-2 nm).
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Registered trials
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