ArticleAngewandte Chemie (International ed. in English)2016
Synthesis of Barbaralones and Bullvalenes Made Easy by Gold Catalysis.
Article in Angewandte Chemie (International ed. in English), 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed.
- Steering the Shape-shifting of Bullvalene-PdAngewandte Chemie (International ed. in English) · 2026Article
- Shape-Shifting Molecules: Unveiling the Valence Tautomerism Phenomena in Bare Barbaralones.Angewandte Chemie (International ed. in English) · 2022Article
- Guest-Dependent Isomer Convergence of a Permanently Fluxional Coordination Cage.Angewandte Chemie (International ed. in English) · 2022Article
- Hypervalent iodine promoted the synthesis of cycloheptatrienes and cyclopropanes.Chemical science · 2022Article
- Homogeneous Gold-Catalyzed Oxidation Reactions.Chemical reviews · 2021Review
- Gold-Catalyzed Synthesis of Small Rings.Chemical reviews · 2021Article
- Rh(II)-Catalyzed Alkynylcyclopropanation of Alkenes by Decarbenation of Alkynylcycloheptatrienes.Journal of the American Chemical Society · 2021Article
- Shapeshifting molecules: the story so far and the shape of things to come.Chemical science · 2020Review
- Shape-selective crystallisation of fluxional carbon cages.Chemical science · 2018Article
- Cyclopropanation of Benzene Rings by Oxidatively Generated α-Oxo Gold Carbene: One-Pot Access to Tetrahydropyranone-Fused Cycloheptatrienes from Propargyl Benzyl Ethers.Advanced synthesis & catalysis · 2018Article
- StereoselectiveACS catalysis · 2017Article
- Synthesis of Barbaralones and Bullvalenes Made Easy by Gold Catalysis.Angewandte Chemie (International ed. in English) · 2016Article
Corrections and comments
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Authors and funding
2 authors.
Funding
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Abstract
The gold(I)-catalyzed oxidative cyclization of 7-ethynyl-1,3,5-cycloheptatrienes gives 1-substituted barbaralones in a general manner, which simplifies the access to other fluxional molecules. As an example, we report the shortest syntheses of bullvalene, phenylbullvalene, and disubstituted bullvalenes, and a readily accessible route to complex cage-type structures by further gold(I)-catalyzed reactions.
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Registered trials
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