ArticleOrganic letters2016
Selective and Serial Suzuki-Miyaura Reactions of Polychlorinated Aromatics with Alkyl Pinacol Boronic Esters.
Article in Organic letters, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Photoinduced Deoxygenative Boration of Unactivated Alcohols Involving In-Situ-Formed Alkyl Iodides.Organic letters · 2025Article
- Directed Photochemically Mediated Nickel-Catalyzed (Hetero)arylation of Aliphatic C-H Bonds.Journal of the American Chemical Society · 2023Article
- Article
- Diversity-oriented synthesis of peptide-boronic acids by a versatile building-block approach.Chemical science · 2020Article
- Photochemically Mediated Nickel-Catalyzed Synthesis ofThe Journal of organic chemistry · 2020Article
- Photochemically-Mediated, Nickel-Catalyzed Synthesis ofOrganic letters · 2019Article
- Exhaustive Suzuki-Miyaura reactions of polyhalogenated heteroarenes with alkyl boronic pinacol esters.Chemical communications (Cambridge, England) · 2017Article
- Decarboxylative borylation.Science (New York, N.Y.) · 2017Article
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Authors and funding
3 authors.
Funding
Abstract
Among cross-coupling reactions, the Suzuki-Miyaura transformation stands out because of its practical advantages, including the commercial availability and low toxicity of the required reagents, mild reaction conditions, and functional group compatibility. Nevertheless, few conditions can be used to cross-couple alkyl boronic acids or esters with aryl halides, especially 2-pyridyl halides. Herein, we describe two novel Suzuki-Miyaura protocols that enable selective conversion of polychlorinated aromatics, with a focus on reactions to convert 2,6-dichloropyridines to 2-chloro-6-alkylpyridines or 2-aryl-6-alkylpyridines.
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Registered trials
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