Evidence map›Paper›PMID 27530633›Full record

ArticleJournal of fluorescence2016

Fluorescent Properties of BODIPY Sensors Based on Photoinduced Electron Transfer.

Yu S Marfin, M V Shipalova, V O Kurzin, K V Ksenofontova, A V Solomonov, E V Rumyantsev

Abstract read
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Article in Journal of fluorescence, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Yu S MarfinDepartment of Inorganic Chemistry, Ivanovo State University of Chemistry and Technology, 7 Sheremetevsky av, 153000, Ivanovo, Russia. ymarfin@gmail.com.
M V ShipalovaDepartment of Inorganic Chemistry, Ivanovo State University of Chemistry and Technology, 7 Sheremetevsky av, 153000, Ivanovo, Russia.
V O KurzinDepartment of Inorganic Chemistry, Ivanovo State University of Chemistry and Technology, 7 Sheremetevsky av, 153000, Ivanovo, Russia.
K V KsenofontovaDepartment of Inorganic Chemistry, Ivanovo State University of Chemistry and Technology, 7 Sheremetevsky av, 153000, Ivanovo, Russia.
A V SolomonovDepartment of Inorganic Chemistry, Ivanovo State University of Chemistry and Technology, 7 Sheremetevsky av, 153000, Ivanovo, Russia.
E V RumyantsevDepartment of Inorganic Chemistry, Ivanovo State University of Chemistry and Technology, 7 Sheremetevsky av, 153000, Ivanovo, Russia.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Two boron-dipyrrin (BODIPY) based dyes with dimethylaminophenyl and carboxyphenyl substituents in 8-position of dipyrrin ligand have been synthesized and characterized. Photophysical and spectral properties of the obtained compounds have been investigated in water-ethanol mixture and water-cyclohexane system with variation of pH values. The equilibria constants of the compounds were identified by classical methods of acid-base titration. BODIPY bearing dimethylaminophenyl and carboxyphenyl subunits show deprotonation/protonation dependent fluorescence off/on-switching. The change of the emission could be mechanistically explained by a PET (photoinduced electron transfer) from the 8-substituent to the fluorophore. The present study demonstrates that BODIPY-based fluorescent sensors can be used to measure the pH in the range of 2-13 extending the scope of BODIPY dyes available as pH-indicators. Investigated compounds demonstrate weak dye-dye interaction allowing their cooperative usage as indicators.

Indexed as

BODIPYComputer modelingElectron-transferFluorescencepH-sensor

Identifiers

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.