ArticleChemistry (Weinheim an der Bergstrasse, Germany)2016
α,β-Unsaturated Gold(I) Carbenes by Tandem Cyclization and 1,5-Alkoxy Migration of 1,6-Enynes: Mechanisms and Applications.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
9 citing papers in PubMed.
- Recent advances in enyne cycloisomerization using N-heterocyclic carbene gold complexes.RSC advances · 2025Review
- Gold(I)-Catalyzed 1,6-Enyne Single-Cleavage Rearrangements: The Complete Picture.ACS organic & inorganic Au · 2023Article
- Gold-Catalyzed Synthesis of Small Rings.Chemical reviews · 2021Article
- Assembly of Complex 1,4-Cycloheptadienes by (4+3) Cycloaddition of Rhodium(II) and Gold(I) Non-Acceptor Carbenes.Angewandte Chemie (International ed. in English) · 2021Article
- Ionization of gold (γ-methoxy)vinyl complexes generates reactive gold vinyl carbene complexes.Chemical science · 2019Article
- Computational Exploration of Counterion Effects in Gold(I)-Catalyzed Cycloisomerization ofACS omega · 2018Article
- StereoselectiveACS catalysis · 2017Article
- Gold-Catalyzed Vinyl Ether Hydroalkynylation: An Alternative Pathway for the Gold-Catalyzed Intermolecular Reaction of Alkenes and Alkynes.Organic letters · 2016Article
- α,β-Unsaturated Gold(I) Carbenes by Tandem Cyclization and 1,5-Alkoxy Migration of 1,6-Enynes: Mechanisms and Applications.Chemistry (Weinheim an der Bergstrasse, Germany) · 2016Article
Corrections and comments
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
1,6-Enynes bearing OR groups at the propargyl position generate α,β-unsaturated gold(I)-carbenes/ gold(I) stabilized allyl cations that can be trapped by alkenes to form cyclopropanes or 1,3-diketones to give products of α-alkylation. The best migrating group is p-nitrophenyl ether, which leads to the corresponding products without racemization. Thus, an improved formal synthesis of (+)-schisanwilsonene A has been accomplished. The different competitive reaction pathways have been delineated computationally.
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