ArticleDental materials : official publication of the Academy of Dental Materials2016
Reduced shrinkage stress via photo-initiated copper(I)-catalyzed cycloaddition polymerizations of azide-alkyne resins.
Article in Dental materials : official publication of the Academy of Dental Materials, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed.
- Chemical Strategies for Reducing Polymerization Shrinkage Stress in Experimental Dental Resin-Based Materials: A Scoping Review.Dentistry journal · 2026Review
- The Incorporation of Copper-Doped Bioactive Glass Nanoparticles into Resin Composites Improves Their Biological, Mechanical and Adhesive Properties.The journal of adhesive dentistry · 2025Article
- Utilizing a degradation prediction pathway system to understand how a novel methacrylate derivative polymer with flipped external ester groups retains physico-mechanical properties following esterase exposure.Dental materials : official publication of the Academy of Dental Materials · 2022Article
- Metal Oxide Nanoparticles and Nanotubes: Ultrasmall Nanostructures to Engineer Antibacterial and Improved Dental Adhesives and Composites.Bioengineering (Basel, Switzerland) · 2021Review
- Photoclick Chemistry: A Bright Idea.Chemical reviews · 2021Review
- Molecular Interactions between Saliva and Dental Composites Resins: A Way Forward.Materials (Basel, Switzerland) · 2021Review
- Photopolymerization shrinkage-stress reduction in polymer-based dental restoratives by surface modification of fillers.Dental materials : official publication of the Academy of Dental Materials · 2021Article
- Vinyl sulfonamide based thermosetting composites via thiol-Michael polymerization.Dental materials : official publication of the Academy of Dental Materials · 2020Article
- Dynamic covalent chemistry (DCC) in dental restorative materials: Implementation of a DCC-based adaptive interface (AI) at the resin-filler interface for improved performance.Dental materials : official publication of the Academy of Dental Materials · 2020Article
- Toward dental caries: Exploring nanoparticle-based platforms and calcium phosphate compounds for dental restorative materials.Bioactive materials · 2019Review
- Dynamic Covalent Chemistry at Interfaces: Development of Tougher, Healable Composites through Stress Relaxation at the Resin-Silica Nanoparticles Interface.Advanced materials interfaces · 2018Article
- Dental Restorative Materials Based on Thiol-Michael Photopolymerization.Journal of dental research · 2018Article
- Evaluation of biofilm formation on novel copper-catalyzed azide-alkyne cycloaddition (CuAAC)-based resins for dental restoratives.Dental materials : official publication of the Academy of Dental Materials · 2018Article
- Fully recoverable rigid shape memory foam based on copper-catalyzed azide-alkyne cycloaddition (CuAAC) using a salt leaching technique.Polymer chemistry · 2018Article
- New Resins for Dental Composites.Journal of dental research · 2017Review
- One-pot blue-light triggered tough interpenetrating polymeric network (IPN) using CuAAC and methacrylate reactions.Polymer chemistry · 2017Article
- Kinetics and mechanics of photo-polymerized triazole-containing thermosetting composites via the copper(I)-catalyzed azide-alkyne cycloaddition.Dental materials : official publication of the Academy of Dental Materials · 2017Article
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7 authors.
Funding
Abstract
objectivesPolymerization shrinkage stress and factors involved in the stress development such as volumetric shrinkage and modulus were investigated in photo-CuAAC (photo-initiated copper(I)-catalyzed azide-alkyne cycloaddition) polymerization and compared with conventional BisGMA-based methacrylate polymerization for their use as alternative dental resins.
methodsTri-functional alkyne and di-functional azide monomers were synthesized for photo-CuAAC polymerization. Conversion kinetics, stress development and polymerization shrinkage were determined with FTIR spectroscopy, tensometery, and with a linometer, respectively, for CuAAC and BisGMA-based monomer mixtures using a camphorquinone/amine visible light photoinitiator system. Thermo-mechanical properties for the cured polymer matrices were characterized by dynamic mechanical analysis and in three-point bending on a universal testing machine. Polymerization kinetics, polymerization shrinkage stress, dynamic volumetric shrinkage, glass transition temperature (T
resultsA glassy CuAAC polymer (T SIGNIFICANCE: CuAAC crosslinked networks possessed high toughness and low polymerization shrinkage stress with quantitative conversion, which eliminated obstacles associated with BisGMA-based dental resins including limited conversion, unreacted extractable moieties, brittle failure, and high shrinkage stress.
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