ArticleNature communications2016
Dehydrogenation of anhydrous methanol at room temperature by o-aminophenol-based photocatalysts.
Article in Nature communications, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed, 38 citations in OpenAlex.
- Iron ion enables photocatalytic hydrogen evolution from methanol.Communications chemistry · 2026Article
- Photocatalytic Aqueous Reforming of Methyl Formate.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Atomic Scale Engineering of Multivalence-State Palladium Photocatalyst for Transfer Hydrogenation with Water as a Proton Source.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Acidic graphene organocatalyst for the superior transformation of wastes into high-added-value chemicals.Nature communications · 2023Article
- Direct Photochemical C-H Carboxylation of Aromatic Diamines with COScientific reports · 2018Article
- A Stable Manganese Pincer Catalyst for the Selective Dehydrogenation of Methanol.Angewandte Chemie (International ed. in English) · 2017Article
Corrections and comments
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Authors and funding
4 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Dehydrogenation of anhydrous methanol is of great importance, given its ubiquity as an intermediate for the production of a large number of industrial chemicals. Since dehydrogenation of methanol is an endothermic reaction, heterogeneous or homogeneous precious-metal-based catalysts and high temperatures are usually required for this reaction to proceed. Here we report the photochemical dehydrogenation of anhydrous methanol at room temperature catalysed by o-aminophenol (apH2), o-aminophenolate (apH(-)) and the non-precious metal complex trans-[Fe(II)(apH)2(MeOH)2]. Under excitation at 289±10 nm and in the absence of additional photosensitizers, these photocatalysts generate hydrogen and formaldehyde from anhydrous methanol with external quantum yields of 2.9±0.15%, 3.7±0.19% and 4.8±0.24%, respectively, which are the highest values reported so far to the best of our knowledge. Mechanistic investigations reveal that the photo-induced formation of hydrogen radicals triggers the reaction.
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Registered trials
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