ArticleAngewandte Chemie (International ed. in English)2016
Catalytic Enantioselective Conjugate Additions of (pin)B-Substituted Allylcopper Compounds Generated in situ from Butadiene or Isoprene.
Article in Angewandte Chemie (International ed. in English), 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
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Who cites it
21 citing papers in PubMed.
- Enantioselective Synthesis of 2,3-Disubstituted Azetidines via Copper-Catalyzed Boryl Allylation of Azetines.Journal of the American Chemical Society · 2025Article
- Approach Toward Stereoselective α-Arylation by Pd/Cu-Catalyzed Arylboration of Electron Deficient Alkenes.Angewandte Chemie (International ed. in English) · 2025Article
- Copper-Catalyzed Asymmetric Acylboration of 1,3-Butadienylboronate with Acyl Fluorides.Angewandte Chemie (International ed. in English) · 2023Article
- Copper-catalysed asymmetric reductive cross-coupling of prochiral alkenes.Nature communications · 2022Article
- Recent Advances in Catalysis Involving Bidentate N-Heterocyclic Carbene Ligands.Molecules (Basel, Switzerland) · 2021Review
- Photochemical Organocatalytic Regio- and Enantioselective Conjugate Addition of Allyl Groups to Enals.Angewandte Chemie (International ed. in English) · 2021Article
- α- and β-Functionalized Ketones from 1,3-Dienes and Aldehydes: Control of Regio- and Enantioselectivity in Hydroacylation of 1,3-Dienes.Journal of the American Chemical Society · 2021Article
- Copper(I)-catalyzed asymmetric 1,6-conjugate allylation.Nature communications · 2020Article
- Beyond Carbon: Enantioselective and Enantiospecific Reactions with Catalytically Generated Boryl- and Silylcopper Intermediates.ACS central science · 2020Review
- Synthesis of Quaternary Carbon Stereogenic Centers by Diastereoselective Conjugate Addition of Boron-Stabilized Allylic Nucleophiles to Enones.Journal of the American Chemical Society · 2020Article
- Regioselective Arylboration of 1,3-Butadiene.Israel journal of chemistry · 2020Article
- Recent advances in Cu-catalyzed C(spBeilstein journal of organic chemistry · 2020Review
- Ligand-controlled diastereodivergent, enantio- and regioselective copper-catalyzed hydroxyalkylboration of 1,3-dienes with ketones.Chemical science · 2019Article
- Catalytic Enantioselective Addition of an Allyl Group to Ketones Containing a Tri-, a Di-, or a Monohalomethyl Moiety. Stereochemical Control Based on Distinctive Electronic and Steric Attributes of C-Cl, C-Br, and C-F Bonds.Journal of the American Chemical Society · 2019Article
- Racemic Vinylallenes in Catalytic Enantioselective Multicomponent Processes: Rapid Generation of Complexity through 1,6-Conjugate Additions.Angewandte Chemie (International ed. in English) · 2019Article
- Catalytic Hydrothiolation: Regio- and Enantioselective Coupling of Thiols and Dienes.Journal of the American Chemical Society · 2018Article
- Copper-catalyzed enantioselective 1,2-borylation of 1,3-dienes.Chemical science · 2018Article
- Copper-Catalyzed Heteroarylboration of 1,3-Dienes with 3-Bromopyridines: A cine Substitution.Angewandte Chemie (International ed. in English) · 2018Article
- Catalyst Controlled Regiodivergent Arylboration of Dienes.Journal of the American Chemical Society · 2017Article
- Regioselective Arylboration of Isoprene and Its Derivatives by Pd/Cu Cooperative Catalysis.Journal of the American Chemical Society · 2017Article
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5 authors.
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Abstract
Multicomponent catalytic enantioselective transformations that entail the combination of butadiene or isoprene (common feedstock), an enoate (prepared in one step) and B2 (pin)2 (commercially available) are presented. These processes constitute an uncommon instance of conjugate addition of an allyl moiety and afford the desired products in up to 83 % yield and 98:2 enantiomeric ratio. Based on DFT calculations stereochemical models and rationale for the observed profiles in selectivity are provided.
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