ArticleAngewandte Chemie (International ed. in English)2016
Selective Nitrate Recognition by a Halogen-Bonding Four-Station [3]Rotaxane Molecular Shuttle.
Article in Angewandte Chemie (International ed. in English), 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
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Who cites it
21 citing papers in PubMed.
- Precision Switching and Coupled Motion in a [3]Rotaxane Molecular Machine.Angewandte Chemie (International ed. in English) · 2026Article
- Tangled Tail of Mechanically Interlocked Peptides.Journal of the American Chemical Society · 2026Review
- Rocking (and Shuttling) in a Nanosized Metallobox.Angewandte Chemie (International ed. in English) · 2025Article
- Probing the Reversible Binding of Anionic Reactive Sulfur and Nitrogen Species in Imidazolium Receptors with Directional C-H Hydrogen Bonds.Inorganic chemistry · 2025Article
- Supramolecular Enhancement of Electrochemical Nitrate Reduction Catalyzed by Cobalt Porphyrin Organic Cages for Ammonia Electrosynthesis in Water.Angewandte Chemie (International ed. in English) · 2023Article
- Dynamic Metalloporphyrin-Based [2]Rotaxane Molecular Shuttles Stimulated by Neutral Lewis Base and Anion Coordination.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- [2+3] Amide Cages by Oxidation of [2+3] Imine Cages - Revisiting Molecular Hosts for Highly Efficient Nitrate Binding.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Selective Potassium Chloride Recognition, Sensing, Extraction, and Transport Using a Chalcogen-Bonding Heteroditopic Receptor.Journal of the American Chemical Society · 2022Article
- Halogen bonding and chalcogen bonding mediated sensing.Chemical science · 2022Review
- Halogen bonding regulated functional nanomaterials.Nanoscale advances · 2021Review
- Halogen-Bonding Strapped Porphyrin BODIPY Rotaxanes for Dual Optical and Electrochemical Anion Sensing.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Selective Anion Binding Drives the Formation of AgJournal of the American Chemical Society · 2021Article
- Separation of halogenated benzenes enabled by investigation of halogen-π interactions with carbon materials.Chemical science · 2020Article
- Isoselective Lactide Ring Opening Polymerisation using [2]Rotaxane Catalysts.Angewandte Chemie (International ed. in English) · 2019Article
- Step-by-step reaction-powered mechanical motion triggered by a chemical fuel pulse.Chemical science · 2019Article
- Methanesulfonyl-polarized halogen bonding enables strong halide recognition in an arylethynyl anion receptor.Chemical communications (Cambridge, England) · 2019Article
- Differential Binding of Tetrel-Bonding Bipodal Receptors to Monatomic and Polyatomic Anions.Molecules (Basel, Switzerland) · 2019Article
- Ring-through-ring molecular shuttling in a saturated [3]rotaxane.Nature chemistry · 2018Article
- Tetrel Bonding as a Vehicle for Strong and Selective Anion Binding.Molecules (Basel, Switzerland) · 2018Article
- A Fluorescent Ditopic Rotaxane Ion-Pair Host.Angewandte Chemie (International ed. in English) · 2018Article
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5 authors.
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Abstract
The synthesis of the first halogen bonding [3]rotaxane host system containing a bis-iodo triazolium-bis-naphthalene diimide four station axle component is reported. Proton NMR anion binding titration experiments revealed the halogen bonding rotaxane is selective for nitrate over the more basic acetate, hydrogen carbonate and dihydrogen phosphate oxoanions and chloride, and exhibits enhanced recognition of anions relative to a hydrogen bonding analogue. This elaborate interlocked anion receptor functions via a novel dynamic pincer mechanism where upon nitrate anion binding, both macrocycles shuttle from the naphthalene diimide stations at the periphery of the axle to the central halogen bonding iodo-triazolium station anion recognition sites to form a unique 1:1 stoichiometric nitrate anion-rotaxane sandwich complex. Molecular dynamics simulations carried out on the nitrate and chloride halogen bonding [3]rotaxane complexes corroborate the (1) H NMR anion binding results.
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