ArticleNature communications2016
Catalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand.
Article in Nature communications, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 47 papers.
What it found
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Who cites it
47 citing papers in PubMed, 290 citations in OpenAlex.
- Redox State-Dependent Dinitrogen Binding by an Isocyanide Analogue of 15eAngewandte Chemie (International ed. in English) · 2026Article
- Machine Learning Accelerated Computational Design of Bio-Inspired Catalysts in the Nitrogen Reduction Reaction.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Remote Positioning of Cations Tunes Catalytic Fe-Mediated Nitrogen Fixation Selectivity for Hydrazine Instead of Ammonia in Protic Media.Angewandte Chemie (International ed. in English) · 2026Article
- Investigating NChemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- A Dinitrogen Complex without Donor Ligands: Isolation and Characterization of a [Mn(CO)Journal of the American Chemical Society · 2025Article
- Anion-Exchange Strategy for Ru/RuOPolymers · 2025Article
- Synthesis and electrochemical properties of molybdenum nitrido complexes supported by redox-active NHC and MIC ligands.Dalton transactions (Cambridge, England : 2003) · 2025Article
- Low-Coordinate Iron Hydride Chemistry at an N,N,C-Heteroscorpionate Platform.Inorganic chemistry · 2024Article
- Alkaline earth metal-assisted dinitrogen activation at nickel.Dalton transactions (Cambridge, England : 2003) · 2024Article
- Electrocatalytic Reduction of Dinitrogen to Ammonia with Water as Proton and Electron Donor Catalyzed by a Combination of a Tri-ironoxotungstate and an Alkali Metal Cation.Journal of the American Chemical Society · 2023Article
- Cyclopentadienyl ring activation in organometallic chemistry and catalysis.Nature reviews. Chemistry · 2023Review
- LNL-Carbazole Pincer Ligand: More than the Sum of Its Parts.Chemical reviews · 2023Review
- Highly Selective Fe-Catalyzed Nitrogen Fixation to Hydrazine Enabled by Sm(II) Reagents with Tailored Redox Potential and pJournal of the American Chemical Society · 2023Article
- Light Alters the NHAngewandte Chemie (International ed. in English) · 2023Article
- Ammonia from dinitrogen at ambient conditions by organometallic catalysts.RSC advances · 2022Review
- Synthesis and Reactivity of Manganese Complexes Bearing Anionic PNP- and PCP-Type Pincer Ligands toward Nitrogen Fixation.Molecules (Basel, Switzerland) · 2022Article
- Computational Screening of First-Row Transition-Metal Based Alloy Catalysts-Ligand Induced NACS physical chemistry Au · 2022Article
- Bonding and stability of dinitrogen-bonded donor base-stabilized Si(0)/Ge(0) species [(cAACRSC advances · 2022Article
- Estimations of FeRSC advances · 2022Article
- EDA-NOCV Calculation for Efficient NACS omega · 2021Article
Corrections and comments
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Authors and funding
8 authors at 3 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Synthesis and reactivity of iron-dinitrogen complexes have been extensively studied, because the iron atom plays an important role in the industrial and biological nitrogen fixation. As a result, iron-catalyzed reduction of molecular dinitrogen into ammonia has recently been achieved. Here we show that an iron-dinitrogen complex bearing an anionic PNP-pincer ligand works as an effective catalyst towards the catalytic nitrogen fixation, where a mixture of ammonia and hydrazine is produced. In the present reaction system, molecular dinitrogen is catalytically and directly converted into hydrazine by using transition metal-dinitrogen complexes as catalysts. Because hydrazine is considered as a key intermediate in the nitrogen fixation in nitrogenase, the findings described in this paper provide an opportunity to elucidate the reaction mechanism in nitrogenase.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.