ArticleAngewandte Chemie (International ed. in English)2016
A Halogen-Bond-Induced Triple Helicate Encapsulates Iodide.
Article in Angewandte Chemie (International ed. in English), 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 28 papers.
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Who cites it
28 citing papers in PubMed.
- Probing Weak Halogen Bonding in Aqueous Solution.Journal of the American Chemical Society · 2026Article
- Programmable Assembly of Multistranded Helices in Water.Nature communications · 2025Article
- Photoswitching of Co(ii)-based coordination cages containing azobenzene backbones.Chemical science · 2024Article
- Supramolecular "baking powder": a hexameric halogen-bonded phosphonium salt cage encapsulates and functionalises small-molecule carbonyl compounds.Chemical science · 2023Article
- Poly-pnictogen bonding: trapping halide ions by a tetradentate antimony(iii) Lewis acid.Chemical science · 2023Article
- Controlling aromatic helix dimerization in water by tuning charge repulsions.Chemical science · 2023Article
- The interplay between hydrogen and halogen bonding: substituent effects and their role in the hydrogen bond enhanced halogen bond.Chemical science · 2023Article
- High-affinity single and double helical pseudofoldaxanes with cationic guests.Chemical science · 2023Article
- Anti-Hofmeister Anion Selectivity via a Mechanical Bond Effect in Neutral Halogen-Bonding [2]Rotaxanes.Angewandte Chemie (International ed. in English) · 2022Article
- Roles of Metal Ions in Foldamers and Other Conformationally Flexible Supramolecular Systems.ACS organic & inorganic Au · 2022Review
- Formation of supramolecular channels by reversible unwinding-rewinding of bis(indole) double helix via ion coordination.Nature communications · 2022Article
- Halogen bonding and chalcogen bonding mediated sensing.Chemical science · 2022Review
- Article
- Halogen bonding regulated functional nanomaterials.Nanoscale advances · 2021Review
- Transmembrane anion transport mediated by halogen bonding and hydrogen bonding triazole anionophores.Chemical science · 2020Article
- Is There a Single Ideal Parameter for Halogen-Bonding-Based Lewis Acidity?Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Helical Anion Foldamers in Solution.Chemical reviews · 2020Review
- Hydrogen Bond Enhanced Halogen Bonds: A Synergistic Interaction in Chemistry and Biochemistry.Accounts of chemical research · 2019Review
- Anion Influence on the Packing of 1,3-Bis(4-Ethynyl-3-Iodopyridinium)-Benzene Halogen Bond Receptors.Crystals · 2019Article
- Halogen Bonding Helicates Encompassing Iodonium Cations.Angewandte Chemie (International ed. in English) · 2019Article
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6 authors.
Funding
Abstract
The self-assembly of higher-order anion helicates in solution remains an elusive goal. Herein, we present the first triple helicate to encapsulate iodide in organic and aqueous media as well as the solid state. The triple helicate self-assembles from three tricationic arylethynyl strands and resembles a tubular anion channel lined with nine halogen bond donors. Eight strong iodine⋅⋅⋅iodide halogen bonds and numerous buried π-surfaces endow the triplex with remarkable stability, even at elevated temperatures. We suggest that the natural rise of a single-strand helix renders its linear halogen-bond donors non-convergent. Thus, the stringent linearity of halogen bonding is a powerful tool for the synthesis of multi-strand anion helicates.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.