Evidence map›Paper›PMID 27375117›Full record

ArticleChemical communications (Cambridge, England)2016

Harnessing solid-state packing for selective detection of chloride in a macrocyclic anionophore.

Chris L Vonnegut, Airlia M Shonkwiler, Lev N Zakharov, Michael M Haley, Darren W Johnson

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical communications (Cambridge, England), 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
0.7field-weighted citation impact, top 28% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed, 11 citations in OpenAlex.

  1. Dynamic Covalent Self-Assembly of Chloride- and Ion-Pair-Templated Cryptates.Angewandte Chemie (International ed. in English) · 2022
    Article
  2. Solvent-Controlled Self-Assembled Oligopyrrolic Receptor.Molecules (Basel, Switzerland) · 2021
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors at 2 institutions in 2 countries.

Chris L VonnegutDepartment of Chemistry & Biochemistry and Materials Science Institute, University of Oregon, Eugene, OR 97403-1253, USA. haley@uoregon.edu dwj@uoregon.edu.
Airlia M ShonkwilerDepartment of Chemistry & Biochemistry and Materials Science Institute, University of Oregon, Eugene, OR 97403-1253, USA. haley@uoregon.edu dwj@uoregon.edu.
Lev N ZakharovCAMCOR, University of Oregon, 1443 East 13th Ave., Eugene, Oregon 97403, USA.
Michael M HaleyDepartment of Chemistry & Biochemistry and Materials Science Institute, University of Oregon, Eugene, OR 97403-1253, USA. haley@uoregon.edu dwj@uoregon.edu.
Darren W JohnsonDepartment of Chemistry & Biochemistry and Materials Science Institute, University of Oregon, Eugene, OR 97403-1253, USA. haley@uoregon.edu dwj@uoregon.edu.
University of Oregon · USEugene Research Institute · US

Funding

Reducing Susceptibility to Environmental Stress Throughout the Life SpanP30ES000210 · NIEHS · OREGON STATE UNIVERSITY · PI BECKMAN, JOSEPH S · 1985 to 2015
$21.4M
Design of Modular Receptors for Ion and Molecule RecognitionR01GM087398 · NIGMS · UNIVERSITY OF OREGON · PI HALEY, MICHAEL MARK, JOHNSON, DARREN WILLIAM · 2010 to 2020
$2.6M
NIEHS NIH HHS P30 ES000210NIGMS NIH HHS R01 GM087398
6 · The paper itself

Abstract

We report the synthesis of an inherently fluorescent macrocyclic receptor for chloride. The use of a disulphide tether provides for an excellent yield in the macrocyclization step. This compound binds chloride in the solution and solid state, and while unstable over time in aqueous solution, shows a selective response toward chloride over other anions in the solid state due to intermolecular interactions between fluorophore backbones. Surprisingly, the optoelectronic response to anions differs in solution and the films, with a distinct colorimetric response observed only in the film.

Identifiers

PMID27375117
PMCPMC4973467
OpenAlexW2463267589

What OpenQuestion holds

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Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.