ArticleBeilstein journal of organic chemistry2016
The role of alkyl substituents in deazaadenine-based diarylethene photoswitches.
Article in Beilstein journal of organic chemistry, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- On photokinetics under monochromatic light.Frontiers in chemistry · 2023Article
- A DNA-Based Two-Component Excitonic Switch Utilizing High-Performance Diarylethenes.Angewandte Chemie (International ed. in English) · 2022Article
- Development of Red-Shifted and Fluorogenic Nucleoside and Oligonucleotide Diarylethene Photoswitches.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Development of High-Performance Pyrimidine Nucleoside and Oligonucleotide Diarylethene Photoswitches.Angewandte Chemie (International ed. in English) · 2021Article
- Photoswitchable Oligonucleotides Containing Different Diarylethene-Modified Nucleotides.ACS omega · 2019Article
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Authors and funding
3 authors.
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Abstract
Diarylethenes are an important class of reversible photoswitches and often claimed to require two alkyl substituents at the carbon atoms between which the bond is formed or broken in the electrocyclic rearrangement. Here we probe this claim by the synthesis and characterization of four pairs of deazaadenine-based diarylethene photoswitches with either one or two methyl groups at these positions. Depending on the substitution pattern, diarylethenes with one alkyl group can exhibit significant photochromism, but they generally show poor stability towards extended UV irradiation, low thermal stability, and decreased fatigue resistance. The results obtained provide an important direction for the design of new efficient DNA photoswitches for the application in bionanotechnology and synthetic biology.
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