ArticleScientific reports2016
Photochemical Isomerization and Topochemical Polymerization of the Programmed Asymmetric Amphiphiles.
Article in Scientific reports, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Azobenzene Photoswitch in Asymmetric Polydiacetylenes Dictates Molecular Ordering and Soft-Crystalline Transitions.Chemistry, an Asian journal · 2026Article
- Topochemical Ring-Opening Polymerization of an Oxathianethione.Journal of the American Chemical Society · 2025Article
- Photochemically and Thermally Programmed Optical Multi-States from a Single Diacetylene-Functionalized Cyanostilbene Luminogen.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Aptamer-functionalized polydiacetylene biosensor for the detection of three foodborne pathogens.Analytical sciences : the international journal of the Japan Society for Analytical Chemistry · 2024Article
- Photoinduced Reversible Bending and Guest Molecule Release of Azobenzene-Containing Polydiacetylene Nanotubes.Scientific reports · 2019Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
For the advancement in multi-stimuli responsive optical devices, we report the elaborate molecular engineering of the dual photo-functionalized amphiphile (abbreviated as AZ1DA) containing both a photo-isomerizable azobenzene and a photo-polymerizable diacetylene. To achieve the efficient photochemical reactions in thin solid films, the self-assembly of AZ1DA molecules into the ordered phases should be precisely controlled and efficiently utilized. First, the remote-controllable light shutter is successfully demonstrated based on the reversible trans-cis photo-isomerization of azobenzene group in the smectic A mesophase. Second, the self-organized monoclinic crystal phase allows us to validate the photo-polymerization of diacetylene moiety for the photo-patterned thin films and the thermo-responsible color switches. From the demonstrations of optically tunable thin films, it is realized that the construction of strong relationships between chemical structures, molecular packing structures and physical properties of the programmed molecules is the core research for the development of smart and multifunctional soft materials.
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Registered trials
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