ArticleChemistryOpen2016
Mechanism of the Transmetalation of Organosilanes to Gold.
Article in ChemistryOpen, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Understanding the Surprising Oxidation Chemistry of Au-OH Complexes.Chemphyschem : a European journal of chemical physics and physical chemistry · 2023Article
- Gold-Catalyzed C-H Functionalization with Aryl Germanes.ACS catalysis · 2019Article
- Mechanism of the Transmetalation of Organosilanes to Gold.ChemistryOpen · 2016Article
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6 authors.
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Abstract
Density functional theory (DFT) calculations were carried out to study the reaction mechanism of the first transmetalation of organosilanes to gold as a cheap fluoride-free process. The versatile gold(I) complex [Au(OH)(IPr)] permits very straightforward access to a series of aryl-, vinyl-, and alkylgold silanolates by reaction with the appropriate silane reagent. These silanolate compounds are key intermediates in a fluoride-free process that results in the net transmetalation of organosilanes to gold, rather than the classic activation of silanes as silicates using external fluoride sources. However, here we propose that the gold silanolate is not the active species (as proposed during experimental studies) but is, in fact, a resting state during the transmetalation process, as a concerted step is preferred.
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