ReviewChemistryOpen2015
Metal Catalysis in Thiolation and Selenation Reactions of Alkynes Leading to Chalcogen-Substituted Alkenes and Dienes.
Review in ChemistryOpen, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
6 citing papers in PubMed.
- Silylium-Ion-Initiated Disulfidation of Internal Alkynes With Disulfides.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Transition-Metal-Free Thioboration of Terminal Alkynes.JACS Au · 2024Article
- (Molecules (Basel, Switzerland) · 2020Article
- Selectivity control in thiol-yne click reactionsChemical science · 2020Article
- The Alkyne Moiety as a Latent Electrophile in Irreversible Covalent Small Molecule Inhibitors of Cathepsin K.Journal of the American Chemical Society · 2019Article
- Metal Catalysis in Thiolation and Selenation Reactions of Alkynes Leading to Chalcogen-Substituted Alkenes and Dienes.ChemistryOpen · 2015Review
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
1 author.
Funding
No grant is acknowledged in the PubMed record.
Abstract
This review covers recent achievements in metal-catalyzed Z-H and Z-Z (Z=S, Se) bond addition to the triple bonds of alkynes-a convenient and atom-efficient way to carbon-element bond formation. Various catalytic systems (both homogeneous and heterogeneous) developed to date to obtain mono- and bis-chalcogen-substituted alkenes or dienes, as well as carbonyl compounds or heterocycles, starting from simple and available alkynes and chalcogenols or dichalcogenides are described. The right choice of metal and ligands allows us to perform these transformations with high selectivities under mild reaction conditions, thus tolerating unprotected functional groups in substrates and broadening ways of further modification of the products. The main aim of the review is to show the potential of the catalytic methods developed in synthetic organic chemistry. Thus, emphasis is made on the scope of reactions, types of products that can be selectively formed, convenience, and scalability of the catalytic procedures. A brief mechanistic description is also given to introduce new readers to the topic.
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Registered trials
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