ArticleNature communications2016
Polymorphism in magic-sized Au144(SR)60 clusters.
Article in Nature communications, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 39 papers.
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Who cites it
39 citing papers in PubMed.
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- Multiscale Modeling of Broadband Perfect Absorbers Based on Gold Metallic Molecules.ACS omega · 2022Article
- Structural Analysis of Molecular Materials Using the Pair Distribution Function.Chemical reviews · 2022Review
- Advances in the electron diffraction characterization of atomic clusters and nanoparticles.Nanoscale advances · 2021Review
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- Distance makes a difference in crystalline photoluminescence.Nature communications · 2020Article
- Ligand-protected gold/silver superatoms: current status and emerging trends.Chemical science · 2020Review
Corrections and comments
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Authors and funding
7 authors.
Funding
Abstract
Ultra-small, magic-sized metal nanoclusters represent an important new class of materials with properties between molecules and particles. However, their small size challenges the conventional methods for structure characterization. Here we present the structure of ultra-stable Au144(SR)60 magic-sized nanoclusters obtained from atomic pair distribution function analysis of X-ray powder diffraction data. The study reveals structural polymorphism in these archetypal nanoclusters. In addition to confirming the theoretically predicted icosahedral-cored cluster, we also find samples with a truncated decahedral core structure, with some samples exhibiting a coexistence of both cluster structures. Although the clusters are monodisperse in size, structural diversity is apparent. The discovery of polymorphism may open up a new dimension in nanoscale engineering.
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