Evidence map›Paper›PMID 27281290›Full record

ArticleInorganic chemistry2016

Effect of the Mn Oxidation State on Single-Molecule-Magnet Properties: Mn(III) vs Mn(IV) in Biologically Inspired DyMn3O4 Cubanes.

Po-Heng Lin, Emily Y Tsui, Fatemah Habib, Muralee Murugesu, Theodor Agapie

Abstract read
In one paragraph

Article in Inorganic chemistry, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. Article
  2. Article
  3. CaMnAngewandte Chemie (International ed. in English) · 2021
    Article
  4. Article
  5. Tetranuclear [MnJournal of the American Chemical Society · 2018
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Po-Heng LinDivision of Chemistry and Chemical Engineering, California Institute of Technology , Pasadena, California 91125, United States.
Emily Y TsuiDivision of Chemistry and Chemical Engineering, California Institute of Technology , Pasadena, California 91125, United States.
Fatemah HabibDepartment of Chemistry, University of Ottawa , 10 Marie-Curie, Ottawa, Ontario K1N 6N5, Canada.
Muralee MurugesuDepartment of Chemistry, University of Ottawa , 10 Marie-Curie, Ottawa, Ontario K1N 6N5, Canada.
Theodor AgapieDivision of Chemistry and Chemical Engineering, California Institute of Technology , Pasadena, California 91125, United States.

Funding

Synthetic Models of the Oxygen Evolving Complex of Photosystem IIR01GM102687 · NIGMS · CALIFORNIA INSTITUTE OF TECHNOLOGY · PI AGAPIE, THEODOR · 2013 to 2022
$2.4M
NIGMS NIH HHS R01 GM102687
6 · The paper itself

Abstract

Inspired by the ferromagnetic coupling in the cubane model CaMn(IV)3O4 of the oxygen-evolving complex of photosystem II, 3d-4f mixed-metal DyMn3O4 clusters were prepared for investigation of the magnetic properties. For comparison, YMn(IV)3O4 and YMn(IV)2Mn(III)O4 clusters were investigated as well and showed ferromagnetic interactions, like the calcium analogue. DyMn(IV)3O4 displays single-molecule-magnet properties, while the one-electron-reduced species (DyMn(IV)2Mn(III)O4) does not, despite the presence of a Mn(III) center with higher spin and single-ion anisotropy.

Indexed as

Electron Spin Resonance SpectroscopyManganeseOxidation-ReductionManganese

Identifiers

PMID27281290
PMCPMC5510600

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.