ArticleJournal of the American Chemical Society2016
Nickel-Catalyzed Asymmetric Kumada Cross-Coupling of Symmetric Cyclic Sulfates.
Article in Journal of the American Chemical Society, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
8 citing papers in PubMed.
- Enantiospecific cross-coupling of cyclic alkyl sulfones.Nature chemistry · 2024Article
- Simultaneous Dehalogenation and Hydrogenation in Sonogashira Coupling.Precision chemistry · 2023Article
- Paired electrolysis-enabled nickel-catalyzed enantioselective reductive cross-coupling between α-chloroesters and aryl bromides.Nature communications · 2022Article
- Conformational Flexibility as a Tool for Enabling Site-Selective Functionalization of UnactivatedJournal of the American Chemical Society · 2022Article
- DFT insight into asymmetric alkyl-alkyl bond formationChemical science · 2022Article
- Further Developments and Applications of Oxazoline-Containing Ligands in Asymmetric Catalysis.Chemical reviews · 2021Article
- Nickel-Catalyzed Alkyl-Alkyl Cross-Electrophile Coupling Reaction of 1,3-Dimesylates for the Synthesis of Alkylcyclopropanes.Journal of the American Chemical Society · 2020Article
- Transition-metal-free regioselective C-H halogenation of imidazo[1,2-RSC advances · 2018Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
Nickel-catalyzed enantioselective cross-couplings between symmetric cyclic sulfates and aromatic Grignard reagents are described. These reactions are effective with a broad range of substituted cyclic sulfates and deliver products with asymmetric tertiary carbon centers. Mechanistic experiments point to a stereoinvertive SN2-like oxidative addition of a nickel complex to the electrophilic substrate.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.