ReviewChemical reviews2016
Synthesis of Diiron(I) Dithiolato Carbonyl Complexes.
Review in Chemical reviews, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 32 papers.
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Who cites it
32 citing papers in PubMed.
- [FeInorganic chemistry · 2025Article
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- Characterization of Complex-B ([Fe(κJournal of the American Chemical Society · 2025Article
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- Bridging Carbonyl and Carbyne Complexes of Weak-Field Iron: Electronic Structure and Iron-Carbon Bonding.Journal of the American Chemical Society · 2024Article
- The H-cluster of [FeFe] Hydrogenases: Its Enzymatic Synthesis and Parallel Inorganic Semisynthesis.Accounts of chemical research · 2024Article
- Article
- Final Stages in the Biosynthesis of the [FeFe]-Hydrogenase Active Site.Angewandte Chemie (International ed. in English) · 2024Article
- Desulfurization of thiosemicarbazones: the role of metal ions and biological implications.Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry · 2024Review
- Catalytic hydrogenation of olefins by a multifunctional molybdenum-sulfur complex.Nature communications · 2024Article
- Hybrids of [FeFe]- and [NiFe]-HOrganometallics · 2023Article
- Supramolecular Coordination Cages for Artificial Photosynthesis and Synthetic Photocatalysis.Chemical reviews · 2023Review
- Bioinspired Framework Catalysts: From Enzyme Immobilization to Biomimetic Catalysis.Chemical reviews · 2023Review
- Non-Covalent Integration of a [FeFe]-Hydrogenase Mimic to Multiwalled Carbon Nanotubes for Electrocatalytic Hydrogen Evolution.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Novel [FeFe]-Hydrogenase Mimics: Unexpected Course of the Reaction of Ferrocenyl α-Thienyl Thioketone with FeMaterials (Basel, Switzerland) · 2022Article
- Combining metal-metal cooperativity, metal-ligand cooperativity and chemical non-innocence in diiron carbonyl complexes.Chemical science · 2022Article
- A Modular Strategy for Expanding Electron-Sink Capacity in Noncanonical Cluster Assemblies.Inorganic chemistry · 2021Article
- Group VIII Metal Carbonyl Cluster-Boronic Acid Conjugates: Cytotoxicity and Mode of Action Studies.ACS omega · 2021Article
- Hydrogenase Mimics in MAngewandte Chemie (International ed. in English) · 2020Article
- Iron(0)-Mediated Stereoselective (3+2)-Cycloaddition of Thiochalcones via a Diradical Intermediate.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
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2 authors.
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Abstract
Virtually all organosulfur compounds react with Fe(0) carbonyls to give the title complexes. These reactions are reviewed in light of major advances over the past few decades, spurred by interest in Fe2(μ-SR)2(CO)x centers at the active sites of the [FeFe]-hydrogenase enzymes. The most useful synthetic route to Fe2(μ-SR)2(CO)6 involves the reaction of thiols with Fe2(CO)9 and Fe3(CO)12. Such reactions can proceed via mono-, di-, and triiron intermediates. The reactivity of Fe(0) carbonyls toward thiols is highly chemoselective, and the resulting dithiolato complexes are fairly rugged. Thus, many complexes tolerate further synthetic elaboration directed at the organic substituents. A second major route involves alkylation of Fe2(μ-S2)(CO)6, Fe2(μ-SH)2(CO)6, and Li2Fe2(μ-S)2(CO)6. This approach is especially useful for azadithiolates Fe2[(μ-SCH2)2NR](CO)6. Elaborate complexes arise via addition of the FeSH group to electrophilic alkenes, alkynes, and carbonyls. Although the first example of Fe2(μ-SR)2(CO)6 was prepared from ferrous reagents, ferrous compounds are infrequently used, although the Fe(II)(SR)2 + Fe(0) condensation reaction is promising. Almost invariably low-yielding, the reaction of Fe3(CO)12, S8, and a variety of unsaturated substrates results in C-H activation, affording otherwise inaccessible derivatives. Thiones and related C═S-containing reagents are highly reactive toward Fe(0), often giving complexes derived from substituted methanedithiolates and C-H activation.
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