ArticleNature chemistry2016
A supramolecular ruthenium macrocycle with high catalytic activity for water oxidation that mechanistically mimics photosystem II.
Article in Nature chemistry, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 42 papers.
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Who cites it
42 citing papers in PubMed.
- Bromide-Mediated Low-Energy RuAngewandte Chemie (International ed. in English) · 2026Article
- Triphenylamine-Based Supramolecular Coordination Metallacycles.Molecules (Basel, Switzerland) · 2026Review
- Enzyme-Like Synthetic Cleft for Light-Driven Water-Oxidation Catalysis Via an Oxide Relay Pathway.Angewandte Chemie (International ed. in English) · 2026Article
- Secondary Coordination Sphere Effects in Macrocycle-Embedded Mononuclear Ru(bda) Water Oxidation Catalysts.Inorganic chemistry · 2026Article
- Bionic Artificial Leaves Based on AIE-Active Supramolecular Hydrogel for Efficient Photocatalysis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Kinetic Pathway Control in the Synthesis of Well-Defined Ruthenium Coordination Oligomers.Small science · 2025Article
- Bioinspired Water Preorganization in Confined Space for Efficient Water Oxidation Catalysis in Metallosupramolecular Ruthenium Architectures.Accounts of chemical research · 2024Article
- Review
- A Water-Stable Boronate Ester Cage.Journal of the American Chemical Society · 2024Article
- Soluble GdChemical science · 2024Article
- Engineering a molecular ruthenium catalyst into three-dimensional metal covalent organic frameworks for efficient water oxidation.Chemical science · 2023Article
- Supramolecular Coordination Cages for Artificial Photosynthesis and Synthetic Photocatalysis.Chemical reviews · 2023Review
- Folding-Induced Promotion of Proton-Coupled Electron Transfers via Proximal Base for Light-Driven Water Oxidation.Angewandte Chemie (International ed. in English) · 2023Article
- Article
- Self-assembled Ru(bda) Coordination Oligomers as Efficient Catalysts for Visible Light-Driven Water Oxidation in Pure Water.Angewandte Chemie (International ed. in English) · 2022Article
- A Covalent Organic Framework for Cooperative Water Oxidation.Journal of the American Chemical Society · 2022Article
- Photoelectrochemical water oxidation improved by pyridineChemical science · 2022Article
- Acidic open-cage solution containing basic cage-confined nanospaces for multipurpose catalysis.National science review · 2022Article
- Promoting Proton Transfer and Stabilizing Intermediates in Catalytic Water Oxidation via Hydrophobic Outer Sphere Interactions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Mechanistic elucidation of the tandem Diels-Alder/(3 + 2) cycloadditions in the design and syntheses of heterosteroids.Journal of molecular modeling · 2022Article
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4 authors.
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Abstract
Mimicking the ingenuity of nature and exploiting the billions of years over which natural selection has developed numerous effective biochemical conversions is one of the most successful strategies in a chemist's toolbox. However, an inability to replicate the elegance and efficiency of the oxygen-evolving complex of photosystem II (OEC-PSII) in its oxidation of water into O2 is a significant bottleneck in the development of a closed-loop sustainable energy cycle. Here, we present an artificial metallosupramolecular macrocycle that gathers three Ru(bda) centres (bda = 2,2'-bipyridine-6,6'-dicarboxylic acid) that catalyses water oxidation. The macrocyclic architecture accelerates the rate of water oxidation via a water nucleophilic attack mechanism, similar to the mechanism exhibited by OEC-PSII, and reaches remarkable catalytic turnover frequencies >100 s(-1). Photo-driven water oxidation yields outstanding activity, even in the nM concentration regime, with a turnover number of >1,255 and turnover frequency of >13.1 s(-1).
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