ArticleOrganic letters2016
Generation of the Methoxycarbonyl Radical by Visible-Light Photoredox Catalysis and Its Conjugate Addition with Electron-Deficient Olefins.
Article in Organic letters, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed.
- Enantioselective Alkoxycarbonyl-Lactonization of Alkenes via the Merger of Photoredox and Copper Catalysis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Asymmetric cyanoesterification of vinylarenes by electrochemical copper catalysis.Nature communications · 2025Article
- Intramolecular PCET of α-Keto Acids: Synthesis of Trifluoromethyl Ketones via Ketyl Radicals.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- C(spACS catalysis · 2025Article
- Light-Mediated Direct Decarboxylative Giese Aroylations without a Photocatalyst.The Journal of organic chemistry · 2024Article
- Article
- Photoredox-Catalyzed Giese Reactions: Decarboxylative Additions to Cyclic Vinylogous Amides and Esters.Molecules (Basel, Switzerland) · 2022Article
- Efficient access to aliphatic esters by photocatalyzed alkoxycarbonylation of alkenes with alkyloxalyl chlorides.Nature communications · 2021Article
- Heterogeneous photocatalytic cyanomethylarylation of alkenes with acetonitrile: synthesis of diverse nitrogenous heterocyclic compounds.Beilstein journal of organic chemistry · 2021Article
- Acridine Photocatalysis: Insights into the Mechanism and Development of a Dual-Catalytic Direct Decarboxylative Conjugate Addition.ACS catalysis · 2020Article
- Recent advances in photoredox and nickel dual-catalyzed cascade reactions: pushing the boundaries of complexity.Chemical science · 2020Review
- Radical cyanomethylationChemical science · 2019Article
- Acyl Radical Chemistry via Visible-Light Photoredox Catalysis.Synthesis · 2019Article
- Silyl-mediated photoredox-catalyzed Giese reaction: addition of non-activated alkyl bromides.Chemical science · 2018Article
- First use of a divalent lanthanide for visible-light-promoted photoredox catalysis.Chemical science · 2018Article
- Decarboxylative alkylation for site-selective bioconjugation of native proteins via oxidation potentials.Nature chemistry · 2018Article
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
Visible-light photoredox-catalyzed fragmentation of methyl N-phthalimidoyl oxalate allows the direct construction of a 1,4-dicarbonyl structural motif by a conjugate addition of the methoxycarbonyl radical to reactive Michael acceptors. The regioselectivity of the addition of this alkoxyacyl radical species to electron-deficient olefins is heavily influenced by the electronic nature of the acceptor, behavior similar to that exhibited by nucleophilic alkyl radicals.
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Registered trials
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