ArticleAngewandte Chemie (International ed. in English)2016
Polynuclear Gold [Au(I) ]4 , [Au(I) ]8 , and Bimetallic [Au(I) 4 Ag(I) ] Complexes: C-H Functionalization of Carbonyl Compounds and Homogeneous Carbonylation of Amines.
Article in Angewandte Chemie (International ed. in English), 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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6 citing papers in PubMed.
- Directing structural transformation in gold(i)-carborane nanoclusters to unlock ultrafast hypergolic ignition.Chemical science · 2026Article
- Filling the gaps in icosahedral superatomic metal clusters.National science review · 2024Article
- Topological insulator as an efficient catalyst for oxidative carbonylation of amines.Science advances · 2023Article
- Small Gold(I) and Gold(I)-Silver(I) Clusters by C-Si Auration.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Iron-catalyzed urea synthesis: dehydrogenative coupling of methanol and amines.Chemical science · 2018Article
- Polynuclear Gold [Au(I) ]4 , [Au(I) ]8 , and Bimetallic [Au(I) 4 Ag(I) ] Complexes: C-H Functionalization of Carbonyl Compounds and Homogeneous Carbonylation of Amines.Angewandte Chemie (International ed. in English) · 2016Article
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Abstract
The synthesis of tetranuclear gold complexes, a structurally unprecedented octanuclear complex with a planar [Au(I) 8 ] core, and pentanuclear [Au(I) 4 M(I) ] (M=Cu, Ag) complexes is presented. The linear [Au(I) 4 ] complex undergoes C-H functionalization of carbonyl compounds under mild reaction conditions. In addition, [Au(I) 4 Ag(I) ] catalyzes the carbonylation of primary amines to form ureas under homogeneous conditions with efficiencies higher than those achieved by gold nanoparticles.
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