Evidence map›Paper›PMID 27162944›Full record

ArticleACS central science2015

Interaction Potentials of Anisotropic Nanocrystals from the Trajectory Sampling of Particle Motion using in Situ Liquid Phase Transmission Electron Microscopy.

Qian Chen, Hoduk Cho, Karthish Manthiram, Mark Yoshida, Xingchen Ye, A Paul Alivisatos

Abstract read
In one paragraph

Article in ACS central science, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 27 papers.

0numbers the graph read from it
0cells of the map it votes in
27citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

27 citing papers in PubMed.

  1. Article
  2. Review
  3. Article
  4. Review
  5. Review
  6. Nanopipette dynamic microscopy unveils nano coffee ring.Proceedings of the National Academy of Sciences of the United States of America · 2024
    Article
  7. Understanding the mechanisms of anisotropic dissolution in metal oxides by applying radiolysis simulations to liquid-phase TEM.Proceedings of the National Academy of Sciences of the United States of America · 2023
    Article
  8. Review
  9. Article
  10. ACS omega · 2021
    Review
  11. Anomalous nanoparticle surface diffusion in LCTEM is revealed by deep learning-assisted analysis.Proceedings of the National Academy of Sciences of the United States of America · 2021
    Article
  12. Article
  13. Article
  14. Article
  15. Complex Nanoparticle Diffusional Motion in Liquid-Cell Transmission Electron Microscopy.The journal of physical chemistry. C, Nanomaterials and interfaces · 2020
    Article
  16. Article
  17. Article
  18. Article
  19. Review
  20. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Qian ChenMiller Institute for Basic Research in Science, Department of Chemistry, Kavli Energy NanoScience Institute, and Department of Chemical Engineering, University of California, Berkeley, California 94720, United States; Miller Institute for Basic Research in Science, Department of Chemistry, Kavli Energy NanoScience Institute, and Department of Chemical Engineering, University of California, Berkeley, California 94720, United States; Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.
Hoduk ChoMiller Institute for Basic Research in Science, Department of Chemistry, Kavli Energy NanoScience Institute, and Department of Chemical Engineering, University of California, Berkeley, California 94720, United States; Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States; King Abdulaziz City for Science and Technology, Kingdom of Saudi Arabia.
Karthish ManthiramMaterials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States; Miller Institute for Basic Research in Science, Department of Chemistry, Kavli Energy NanoScience Institute, and Department of Chemical Engineering, University of California, Berkeley, California 94720, United States.
Mark YoshidaMiller Institute for Basic Research in Science, Department of Chemistry, Kavli Energy NanoScience Institute, and Department of Chemical Engineering, University of California , Berkeley, California 94720, United States.
Xingchen YeMiller Institute for Basic Research in Science, Department of Chemistry, Kavli Energy NanoScience Institute, and Department of Chemical Engineering, University of California, Berkeley, California 94720, United States; Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.
A Paul AlivisatosMiller Institute for Basic Research in Science, Department of Chemistry, Kavli Energy NanoScience Institute, and Department of Chemical Engineering, University of California, Berkeley, California 94720, United States; Miller Institute for Basic Research in Science, Department of Chemistry, Kavli Energy NanoScience Institute, and Department of Chemical Engineering, University of California, Berkeley, California 94720, United States; Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States; King Abdulaziz City for Science and Technology, Kingdom of Saudi Arabia.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

We demonstrate a generalizable strategy to use the relative trajectories of pairs and groups of nanocrystals, and potentially other nanoscale objects, moving in solution which can now be obtained by in situ liquid phase transmission electron microscopy (TEM) to determine the interaction potentials between nanocrystals. Such nanoscale interactions are crucial for collective behaviors and applications of synthetic nanocrystals and natural biomolecules, but have been very challenging to measure in situ at nanometer or sub-nanometer resolution. Here we use liquid phase TEM to extract the mathematical form of interaction potential between nanocrystals from their sampled trajectories. We show the power of this approach to reveal unanticipated features of nanocrystal-nanocrystal interactions by examining the anisotropic interaction potential between charged rod-shaped Au nanocrystals (Au nanorods); these Au nanorods assemble, in a tip-to-tip fashion in the liquid phase, in contrast to the well-known side-by-side arrangements commonly observed for drying-mediated assembly. These observations can be explained by a long-range and highly anisotropic electrostatic repulsion that leads to the tip-selective attachment. As a result, Au nanorods stay unassembled at a lower ionic strength, as the electrostatic repulsion is even longer-ranged. Our study not only provides a mechanistic understanding of the process by which metallic nanocrystals assemble but also demonstrates a method that can potentially quantify and elucidate a broad range of nanoscale interactions relevant to nanotechnology and biophysics.

Identifiers

PMID27162944
PMCPMC4827565

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.