ArticleAngewandte Chemie (International ed. in English)2016
Reductive Umpolung of Carbonyl Derivatives with Visible-Light Photoredox Catalysis: Direct Access to Vicinal Diamines and Amino Alcohols via α-Amino Radicals and Ketyl Radicals.
Article in Angewandte Chemie (International ed. in English), 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 28 papers.
What it found
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Who cites it
28 citing papers in PubMed, 207 citations in OpenAlex.
- Efficient and scalable photochemical coupling of pinacol and aza-pinacol in continuous-flow.Communications chemistry · 2026Article
- Photocatalytic coupling of phenols with iminesOrganic chemistry frontiers : an international journal of organic chemistry · 2026Article
- The Effect of Aldehyde and Carboxylic Acid Substitution on the Isomerization of Hemithioindigo Photoswitches.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Aldehyde-Olefin Couplings Via Sulfoxylate-Mediated Oxidative Generation of Ketyl Radical Anions.Journal of the American Chemical Society · 2024Article
- Silyl Radicals as Single-Electron Reductants: α-Aminoalkyl Radical Formation via a Photocatalytic Oxidatively Initiated Radical Chain Process.Journal of the American Chemical Society · 2024Article
- Excited-state palladium-catalysed reductive alkylation of imines: scope and mechanism.Chemical science · 2022Article
- Switchable, Reagent-Controlled Diastereodivergent Photocatalytic Carbocyclisation of Imine-Derived α-Amino Radicals.Angewandte Chemie (International ed. in English) · 2021Article
- Visible-light photoredox-catalyzed umpolung carboxylation of carbonyl compounds with CONature communications · 2021Article
- Access to Chiral Diamine Derivatives through Stereoselective Cu-Catalyzed Reductive Coupling of Imines and Allenamides.The Journal of organic chemistry · 2021Article
- Allylic C(spChemical science · 2020Article
- Exploiting single-electron transfer in Lewis pairs for catalytic bond-forming reactions.Chemical science · 2020Article
- One Amine-3 Tasks: Reductive Coupling of Imines with Olefins in Batch and Flow.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Distinctive reactivity ofBeilstein journal of organic chemistry · 2020Article
- Reductive Arylation of Arylidene Malonates Using Photoredox Catalysis.ACS catalysis · 2019Article
- 2-Azadienes as Enamine Umpolung Synthons for the Preparation of Chiral Amines.Synlett : accounts and rapid communications in synthetic organic chemistry · 2019Article
- Photoredox-Catalyzed Multicomponent Petasis Reaction with Alkyltrifluoroborates.Organic letters · 2019Article
- Reductive annulations of arylidene malonates with unsaturated electrophiles using photoredox/Lewis acid cooperative catalysis.Chemical science · 2019Article
- Rate-Driving Force Relationships in the Multisite Proton-Coupled Electron Transfer Activation of Ketones.Journal of the American Chemical Society · 2019Article
- Catalytic enantioselective radical coupling of activated ketones withChemical science · 2018Article
- Photocatalytic Barbier reaction - visible-light induced allylation and benzylation of aldehydes and ketones.Chemical science · 2018Article
Corrections and comments
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Authors and funding
5 authors at 1 institution in 2 countries.
Funding
Abstract
Visible-light-mediated photoredox-catalyzed aldimine-aniline and aldehyde-aniline couplings have been realized. The reductive single electron transfer (SET) umpolung of various carbonyl derivatives enabled the generation of intermediary ketyl and α-amino radical anions, which were utilized for the synthesis of unsymmetrically substituted 1,2-diamines and amino alcohols.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.