ArticleAngewandte Chemie (International ed. in English)2016
Electrocatalytic and Solar-Driven CO2 Reduction to CO with a Molecular Manganese Catalyst Immobilized on Mesoporous TiO2.
Article in Angewandte Chemie (International ed. in English), 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
20 citing papers in PubMed.
- Atomically Precise Cluster Cocatalysts: Missing Link toward Heterogenized Photocatalytic Systems.ACS nano · 2026Review
- Photoelectrocatalytic Reduction ofChem · 2025Article
- Comprehensive Review of Synthesis, Optical Properties and Applications of Heteroarylphosphonates and Their Derivatives.Molecules (Basel, Switzerland) · 2024Review
- Conjugated Microporous Polymers for Catalytic COAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Review
- Comprehensive Insights and Advancements in Gel Catalysts for Electrochemical Energy Conversion.Gels (Basel, Switzerland) · 2024Review
- Tuning Electrode Reactivity through Organometallic Complexes.ACS applied materials & interfaces · 2023Review
- Surface-Specific Modification of Graphitic Carbon Nitride by Plasma for Enhanced Durability and Selectivity of Photocatalytic COACS applied materials & interfaces · 2023Article
- Photocatalytic Reduction of COInorganic chemistry · 2022Article
- Manganese Carbonyl Complexes as Selective Electrocatalysts for COAccounts of chemical research · 2022Article
- Charge accumulation kinetics in multi-redox molecular catalysts immobilised on TiOChemical science · 2020Article
- A Precious-Metal-Free Hybrid Electrolyzer for Alcohol Oxidation Coupled to COAngewandte Chemie (International ed. in English) · 2020Article
- Article
- Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes.Chemical reviews · 2019Article
- End-On Bound Iridium Dinuclear Heterogeneous Catalysts on WOACS central science · 2018Article
- Mechanisms of catalytic reduction of COChemical science · 2018Review
- Site-isolated manganese carbonyl on bipyridine-functionalities of periodic mesoporous organosilicas: efficient COChemical science · 2017Article
- Organic, Organometallic and Bioorganic Catalysts for Electrochemical Reduction of COChemphyschem : a European journal of chemical physics and physical chemistry · 2017Review
- Tuning Product Selectivity for Aqueous COJournal of the American Chemical Society · 2017Article
- Photoelectrocatalytic HChemical science · 2017Article
- Electrocatalytic and Solar-Driven CO2 Reduction to CO with a Molecular Manganese Catalyst Immobilized on Mesoporous TiO2.Angewandte Chemie (International ed. in English) · 2016Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Electrocatalytic CO2 reduction to CO was achieved with a novel Mn complex, fac-[MnBr(4,4'-bis(phosphonic acid)-2,2'-bipyridine)(CO)3 ] (MnP), immobilized on a mesoporous TiO2 electrode. A benchmark turnover number of 112±17 was attained with these TiO2 |MnP electrodes after 2 h electrolysis. Post-catalysis IR spectroscopy demonstrated that the molecular structure of the MnP catalyst was retained. UV/vis spectroscopy confirmed that an active Mn-Mn dimer was formed during catalysis on the TiO2 electrode, showing the dynamic formation of a catalytically active dimer on an electrode surface. Finally, we combined the light-protected TiO2 |MnP cathode with a CdS-sensitized photoanode to enable solar-light-driven CO2 reduction with the light-sensitive MnP catalyst.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.