ArticleChemical communications (Cambridge, England)2016
Sc3CH@C80: selective (13)C enrichment of the central carbon atom.
Article in Chemical communications (Cambridge, England), 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Stability and Electronic Properties of Mixed Rare-Earth Tri-Metallofullerenes YxDyMolecules (Basel, Switzerland) · 2024Article
- Stereochemistry of Simple Molecules inside Nanotubes and Fullerenes: Unusual Behavior of Usual Systems.Molecules (Basel, Switzerland) · 2020Review
- Single Molecule Magnetism with Strong Magnetic Anisotropy and Enhanced Dy∙∙∙Dy Coupling in Three Isomers of Dy-Oxide Clusterfullerene DyAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2019Article
- Transformation of doped graphite into cluster-encapsulated fullerene cages.Nature communications · 2017Article
- Selective arc-discharge synthesis of DyChemical science · 2017Article
- Synthesis and Isolation of the Titanium-Scandium Endohedral Fullerenes-Sc2 TiC@Ih -C80 , Sc2 TiC@D5h -C80 and Sc2 TiC2 @Ih -C80 : Metal Size Tuning of the Ti(IV) /Ti(III) Redox Potentials.Chemistry (Weinheim an der Bergstrasse, Germany) · 2016Article
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Authors and funding
3 authors.
Funding
Abstract
Sc3CH@C80 is synthesized and characterized by (1)H, (13)C, and (45)Sc NMR. A large negative chemical shift of the proton, -11.73 ppm in the Ih and -8.79 ppm in the D5h C80 cage isomers, is found. (13)C satellites in the (1)H NMR spectrum enabled indirect determination of the (13)C chemical shift for the central carbon at 173 ± 1 ppm. Intensity of the satellites allowed determination of the (13)C content for the central carbon atom. This unique possibility is applied to analyze the cluster/cage (13)C distribution in mechanistic studies employing either (13)CH4 or (13)C powder to enrich Sc3CH@C80 with (13)C.
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Registered trials
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