ArticleAngewandte Chemie (International ed. in English)2016
Enantioselective, Stereodivergent Hydroazidation and Hydroamination of Allenes Catalyzed by Acyclic Diaminocarbene (ADC) Gold(I) Complexes.
Article in Angewandte Chemie (International ed. in English), 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed.
- Substrate-Controlled Enantiodivergence in Ni-Catalyzed Access to Phosphorylated Oxindoles With Quaternary Stereocenters.Angewandte Chemie (International ed. in English) · 2026Article
- Bidentate Acyclic Diamino Carbene-Stabilized Gold Nanoparticles from Symmetric and Asymmetric Gold(I) Complexes: Synthesis, Characterization, and Catalytic Activity.Inorganic chemistry · 2025Article
- Gold Acyclic Diaminocarbene Complexes as Selective and Potent Agents for Multitarget Cancer Therapy.Inorganic chemistry · 2025Article
- AuInternational journal of molecular sciences · 2025Article
- Synthesis of a New α-Azidomethyl Styrene from Safrole via a Dearomative Rearrangement.Molbank · 2023Article
- Reactivity of Diamines in Acyclic Diamino Carbene Gold Complexes.Inorganic chemistry · 2022Article
- Synthetically Versatile Nitrogen Acyclic Carbene Stabilized Gold Nanoparticles.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Divergent synthesis of chiral cyclic azides via asymmetric cycloaddition reactions of vinyl azides.Nature communications · 2019Article
- Allylic azides: synthesis, reactivity, and the Winstein rearrangement.Organic & biomolecular chemistry · 2019Review
- Enantioselective Synthesis of Trisubstituted Allenyl-B(pin) Compounds by Phosphine-Cu-Catalyzed 1,3-Enyne Hydroboration. Insights Regarding Stereochemical Integrity of Cu-Allenyl Intermediates.Journal of the American Chemical Society · 2018Article
- Parameterization of Acyclic Diaminocarbene Ligands Applied to a Gold(I)-Catalyzed Enantioselective Tandem Rearrangement/Cyclization.Journal of the American Chemical Society · 2017Article
- Chirality Transfer in Gold(I)-Catalysed Hydroalkoxylation of 1,3-Disubstituted Allenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2016Article
- Gold-Catalyzed Vinyl Ether Hydroalkynylation: An Alternative Pathway for the Gold-Catalyzed Intermolecular Reaction of Alkenes and Alkynes.Organic letters · 2016Article
- On the Winstein rearrangement: equilibrium and mechanism.ARKIVOC : free online journal of organic chemistryArticle
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6 authors.
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Abstract
The gold-catalyzed enantioselective hydroazidation and hydroamination reactions of allenes are presented herein. ADC gold(I) catalysts derived from BINAM were critical for achieving high levels of enantioselectivity in both transformations. The sense of enantioinduction is reversed for the two different nucleophiles, allowing access to both enantiomers of the corresponding allylic amines using the same catalyst enantiomer.
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