Evidence map›Paper›PMID 27092011›Full record

ArticleTetrahedron letters2015

Air-Water Interface Effects on the Regioselectivity of Singlet Oxygenations of a Trisubstituted Alkene.

Belaid Malek, Ashwini A Ghogare, Rajib Choudhury, Alexander Greer

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Tetrahedron letters, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
0.3field-weighted citation impact, top 38% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed, 3 citations in OpenAlex.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors at 2 institutions in 1 country.

Belaid MalekDepartment of Chemistry and Graduate Center, City University of New York-Brooklyn College, Brooklyn, New York 11210, United States.
Ashwini A GhogareDepartment of Chemistry and Graduate Center, City University of New York-Brooklyn College, Brooklyn, New York 11210, United States.
Rajib ChoudhuryDepartment of Chemistry and Graduate Center, City University of New York-Brooklyn College, Brooklyn, New York 11210, United States.
Alexander GreerDepartment of Chemistry and Graduate Center, City University of New York-Brooklyn College, Brooklyn, New York 11210, United States.
The Graduate Center, CUNY · USCity University of New York · US

Funding

Site-specific delivery of photosensitizer and singlet oxygen in vivoSC1GM093830 · NIGMS · BROOKLYN COLLEGE · PI GREER, ALEXANDER · 2010 to 2013
$1.5M
NIGMS NIH HHS SC1 GM093830
6 · The paper itself

Abstract

The regioselective synthesis of allylic hydroperoxide sulfonates by singlet oxygenation at the air-water interface has been found to depend on the concentration of the alkene sulfonate and added calcium salt. The regioselectivity is proposed to originate from an orthogonal alkene relative to the water surface for preferential methyl hydrogen abstraction by airborne singlet oxygen in an ene reaction. The findings hint that the air-water interface is a locale for synthetic reactions.

Indexed as

airborne singlet oxygenalkene sulfonateene reactionphase-separationselectivity

Identifiers

PMID27092011
PMCPMC4832427
OpenAlexW597168178

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.