ArticleAngewandte Chemie (International ed. in English)2016
Palladium-Catalyzed Oxidative Carbocyclization-Borylation of Enallenes to Cyclobutenes.
Article in Angewandte Chemie (International ed. in English), 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- Palladium-Catalyzed Site-Selective Regiodivergent Carbocyclization of Di- and Trienallenes: A Switch between Substituted Cyclohexene and Cyclobutene.Journal of the American Chemical Society · 2025Article
- Palladium-Catalyzed Oxidative Allene-Allene Cross-Coupling.Journal of the American Chemical Society · 2025Article
- Regiodivergent Palladium-Catalyzed Alkene Difunctionalization Reactions for the Construction of Methylene Cyclobutanes and Methylene Cyclopentanes.Organic letters · 2022Article
- Iron-Catalyzed Cross-Coupling of Propargyl Ethers with Grignard Reagents for the Synthesis of Functionalized Allenes and Allenols.Angewandte Chemie (International ed. in English) · 2021Article
- Amino-Supported Palladium Catalyst for Chemo- and Stereoselective Domino Reactions.Angewandte Chemie (International ed. in English) · 2021Article
- Access to substituted cyclobutenes by tandem [3,3]-sigmatropic rearrangement/[2 + 2] cycloaddition of dipropargylphosphonates under Ag/Co relay catalysis.Chemical science · 2020Article
- Synthesis of Cross-Conjugated Polyenes via Palladium-Catalyzed Oxidative C-C Bond Forming Cascade Reactions of Allenes.The Journal of organic chemistry · 2020Article
- Efficient Palladium-Catalyzed Aerobic Arylative Carbocyclization of Enallenynes.Angewandte Chemie (International ed. in English) · 2018Article
- Highly selective olefin-assisted palladium-catalyzed oxidative carbocyclizationChemical science · 2017Article
- Highly Efficient Cascade Reaction for Selective Formation of Spirocyclobutenes from Dienallenes via Palladium-Catalyzed Oxidative Double Carbocyclization-Carbonylation-Alkynylation.Journal of the American Chemical Society · 2016Article
- Palladium-Catalyzed Oxidative Carbocyclization-Borylation of Enallenes to Cyclobutenes.Angewandte Chemie (International ed. in English) · 2016Article
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4 authors.
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Abstract
A highly efficient palladium-catalyzed oxidative borylation of enallenes was developed for the selective formation of cyclobutene derivatives and fully-substituted alkenylboron compounds. Cyclobutenes are formed as the exclusive products in MeOH in the presence of H2 O and Et3 N, whereas the use of AcOH leads to alkenylboron compounds. Both reactions showed a broad substrate scope and good tolerance for various functional groups, including carboxylic acid ester, free hydroxy, imide, and alkyl groups. Furthermore, transformations of the borylated products were conducted to show their potential applications.
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