ArticleChemical communications (Cambridge, England)2016
Highly photoluminescent copper carbene complexes based on prompt rather than delayed fluorescence.
Article in Chemical communications (Cambridge, England), 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 11 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
11 citing papers in PubMed.
- Diphosphane-Mediated Control of the Emissive Properties in [Cu(NHC)(P^P)]Inorganic chemistry · 2025Article
- Linear Gold(I) Halide Complexes with a Diamidocarbene Ligand: Synthesis, Reactivity, and Phosphorescence.Organometallics · 2024Article
- The Equilibrium Molecular Structure of Cyclic (Alkyl)(Amino) Carbene Copper(I) Chloride via Gas-Phase Electron Diffraction and Quantum Chemical Calculations.Molecules (Basel, Switzerland) · 2023Article
- Article
- Excited-State Lifetime Modulation by Twisted and Tilted Molecular Design in Carbene-Metal-Amide Photoemitters.Chemistry of materials : a publication of the American Chemical Society · 2022Article
- Reactions of Mesityl Azide with Ferrocene-Based N-Heterocyclic Germylenes, Stannylenes and Plumbylenes, Including PPhChemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Recent Advances in the Domain of Cyclic (Alkyl)(Amino) Carbenes.Chemistry, an Asian journal · 2022Review
- Synthesis and photophysical properties of linear gold(I) complexes based on a CCC carbene.Dalton transactions (Cambridge, England : 2003) · 2021Article
- Isocyanate Insertion into a La-P Phosphide Bond: A Versatile Route to Phosphaureate-Bridged Heterobimetallic Lanthanide-Coinage-Metal Complexes.Inorganic chemistry · 2020Article
- Synthesis and Photophysical Properties of T-Shaped Coinage-Metal Complexes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Carbene metal amide photoemitters: tailoring conformationally flexible amides for full color range emissions including white-emitting OLED.Chemical science · 2020Article
Corrections and comments
- Erratum issued
Authors and funding
10 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Linear two-coordinate copper complexes of cyclic (alkyl)(amino)carbenes (CAAC)CuX (X = halide) show photoluminescence with solid-state quantum yields of up to 96%; in contrast to previously reported Cu photoemitters the emission is independent of temperature over the range T = 4-300 K and occurs very efficiently by prompt rather than delayed fluorescence, with lifetimes in the sub-nanosecond range.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.