ArticleScientific reports2016
Hyper-stable organo-Eu(III) luminophore under high temperature for photo-industrial application.
Article in Scientific reports, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Full Picture of Energy Transfer in a Trivalent Europium Complex with Bidentate β-Diketonate Ligand.The journal of physical chemistry letters · 2024Article
- Highly efficient light harvesting of a Eu(iii) complex in a host-guest film by triplet sensitization.Chemical science · 2023Article
- Structural metamorphosis and photophysical properties of thermostable nano- and microcrystalline lanthanide polymer with flexible coordination chains.Science and technology of advanced materials · 2023Article
- EuFrontiers in chemistry · 2023Review
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Novel organo-Eu(III) luminophores, Eu(hfa)x(CPO)y and Eu(hfa)x(TCPO)y (hfa: hexafluoroacetylacetonate, CPO: 4-carboxyphenyl diphenyl phosphine oxide, TCPO: 4,4',4″-tricarboxyphenyl phosphine oxide), were synthesized by the complexation of Eu(III) ions with hfa moieties and CPO or TCPO ligands. The thermal and luminescent stabilities of the luminophores are extremely high. The decomposition temperature of Eu(hfa)x(CPO)y and Eu(hfa)x(TCPO)y were determined as 200 and 450 °C, respectively. The luminescence of Eu(hfa)x(TCPO)y under UV light irradiation was observed even at a high temperature, 400 °C. The luminescent properties of Eu(hfa)x(CPO)y and Eu(hfa)x(TCPO)y were estimated from emission spectra, quantum yields and lifetime measurements. The energy transfer efficiency from hfa moieties to Eu(III) ions in Eu(hfa)x(TCPO)y was 59%. The photosensitized luminescence of hyper-stable Eu(hfa)x(TCPO)y at 400 °C is demonstrated for future photonic applications.
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Registered trials
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