ArticleSynlett : accounts and rapid communications in synthetic organic chemistry2016
Facile and High-Yielding Synthesis of TAM Biradicals and Monofunctional TAM Radicals.
Article in Synlett : accounts and rapid communications in synthetic organic chemistry, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed, 18 citations in OpenAlex.
- Paramagnetic Agents for SE DNP: Synthesis and ESR Characterization of New Lipophilic Derivatives of Finland Trityl.Molecules (Basel, Switzerland) · 2025Article
- Dynamic Nuclear Polarization Using Electron Spin Cluster.The journal of physical chemistry letters · 2024Article
- Synthesis, Characterization, and Application of a Highly Hydrophilic Triarylmethyl Radical for Biomedical EPR.The Journal of organic chemistry · 2020Article
- Triarylmethyl-based biradical as a superoxide probe.Free radical research · 2018Article
- Triarylmethyl Radicals: EPR Study ofZeitschrift fur physikalische Chemie (Frankfurt am Main, Germany) · 2017Article
- Trityl-based alkoxyamines as NMP controllers and spin-labels.Polymer chemistry · 2016Article
- Electron spin dynamics and spin-lattice relaxation of trityl radicals in frozen solutions.Physical chemistry chemical physics : PCCP · 2016Article
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Authors and funding
6 authors at 3 institutions in 2 countries.
Funding
Abstract
Facile and high-yielding procedures for synthesis of monocarboxylic acid derivatives of triarylmethyl radicals (TAMs) were developed. Reaction of methyl thioglycolate with tris(2,3,5,6-tetrathiaaryl)methyl cation smoothly afforded the monosubstituted TAM derivative, which was hydrolyzed to a monocarboxylic acid, with the TAM moiety attached to thioglycolic acid via the sulfur atom. Alternatively, the diamagnetic tricarboxylic acid precursor of Finland trityl was transformed to a trimethyl ester and partially hydrolyzed under controlled conditions. The diester product was isolated and the remaining fractions were converted back to the trimethyl ester for production of more diester. The first representatives of TAM biradicals with different TAM cores and interspin distances were obtained by reaction of these new TAM monocaboxylic acids with N,N'-dimethylethylenediamine.
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