ArticleAngewandte Chemie (International ed. in English)2016
Photoelectrochemical H2 Evolution with a Hydrogenase Immobilized on a TiO2 -Protected Silicon Electrode.
Article in Angewandte Chemie (International ed. in English), 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed.
- Bio-hybrid photoelectrochemical catalysis for solar fuels and chemicals conversion.Nature communications · 2025Review
- Embedding biocatalysts in a redox polymer enhances the performance of dye-sensitized photocathodes in bias-free photoelectrochemical water splitting.Nature communications · 2024Article
- Advanced Electroanalysis for Electrosynthesis.ACS organic & inorganic Au · 2024Review
- Facile Functionalization of Carbon Electrodes for Efficient Electroenzymatic Hydrogen Production.JACS Au · 2023Article
- Elucidating Film Loss and the Role of Hydrogen Bonding of Adsorbed Redox Enzymes by Electrochemical Quartz Crystal Microbalance Analysis.ACS catalysis · 2022Article
- Review
- Enzymatic photoelectrochemical bioassay based on hierarchical CdS/NiO heterojunction for glucose determination.Mikrochimica acta · 2021Article
- A Tandem Solar Biofuel Cell: Harnessing Energy from Light and Biofuels.Angewandte Chemie (International ed. in English) · 2021Article
- Integration of a Hydrogenase in a Lead Halide Perovskite Photoelectrode for Tandem Solar Water Splitting.ACS energy letters · 2020Article
- Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes.Chemical reviews · 2019Article
- Photoelectrocatalytic HChemical science · 2019Article
- Interfacing nature's catalytic machinery with synthetic materials for semi-artificial photosynthesis.Nature nanotechnology · 2018Review
- Solar Water Splitting with a Hydrogenase Integrated in Photoelectrochemical Tandem Cells.Angewandte Chemie (International ed. in English) · 2018Article
- Engineering the Surface/Interface Structures of Titanium Dioxide Micro and Nano Architectures towards Environmental and Electrochemical Applications.Nanomaterials (Basel, Switzerland) · 2017Review
- Silicon Nanowire Photocathodes for Photoelectrochemical Hydrogen Production.Nanomaterials (Basel, Switzerland) · 2016Article
- Photoelectrochemical H2 Evolution with a Hydrogenase Immobilized on a TiO2 -Protected Silicon Electrode.Angewandte Chemie (International ed. in English) · 2016Article
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4 authors.
Funding
Abstract
The combination of enzymes with semiconductors enables the photoelectrochemical characterization of electron-transfer processes at highly active and well-defined catalytic sites on a light-harvesting electrode surface. Herein, we report the integration of a hydrogenase on a TiO2 -coated p-Si photocathode for the photo-reduction of protons to H2 . The immobilized hydrogenase exhibits activity on Si attributable to a bifunctional TiO2 layer, which protects the Si electrode from oxidation and acts as a biocompatible support layer for the productive adsorption of the enzyme. The p-Si|TiO2 |hydrogenase photocathode displays visible-light driven production of H2 at an energy-storing, positive electrochemical potential and an essentially quantitative faradaic efficiency. We have thus established a widely applicable platform to wire redox enzymes in an active configuration on a p-type semiconductor photocathode through the engineering of the enzyme-materials interface.
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