ArticleScientific reports2016
Clustering mechanism of ethanol-water mixtures investigated with photothermal microfluidic cantilever deflection spectroscopy.
Article in Scientific reports, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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4 citing papers in PubMed, 32 citations in OpenAlex.
- Exploring the effect of ethanol-water structuring on the transport properties of ethanol in porous silicas.Magnetic resonance letters · 2026Article
- Thin Film Analysis by Nanomechanical Infrared Spectroscopy.ACS omega · 2019Article
- Spectroscopic and Thermodynamic Study of Biopolymer Adsorption Phenomena in Heterogeneous Solid-Liquid Systems.ACS omega · 2018Article
- Dynamic Behaviors of Condensing Clusters Based on Rayleigh Scattering Experiment.Scientific reports · 2017Article
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Authors and funding
5 authors at 1 institution in 1 country.
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Abstract
The infrared-active (IR) vibrational mode of ethanol (EtOH) associated with the asymmetrical stretching of the C-C-O bond in pico-liter volumes of EtOH-water binary mixtures is calorimetrically measured using photothermal microfluidic cantilever deflection spectroscopy (PMCDS). IR absorption by the confined liquid results in wavelength dependent cantilever deflections, thus providing a complementary response to IR absorption revealing a complex dipole moment dependence on mixture concentration. Solvent-induced blue shifts of the C-C-O asymmetric vibrational stretch for both anti and gauche conformers of EtOH were precisely monitored for EtOH concentrations ranging from 20-100% w/w. Variations in IR absorption peak maxima show an inverse dependence on induced EtOH dipole moment (μ) and is attributed to the complex clustering mechanism of EtOH-water mixtures.
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