ArticleChemical communications (Cambridge, England)2016
Metal-free C(sp(3))-H functionalization: oxidative carbo-oxygenation of α-diazo carbonyls via radical dediazotization.
Article in Chemical communications (Cambridge, England), 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
8 citing papers in PubMed.
- General Synthesis ofJournal of the American Chemical Society · 2023Article
- Electrochemical oxidative difunctionalization of diazo compounds with two different nucleophiles.Nature communications · 2023Article
- Photochemical synthesis of 1,2,4-triazolesChemical science · 2022Article
- Multicomponent Reactions Involving Diazo Reagents: A 5-Year Update.Molecules (Basel, Switzerland) · 2021Review
- Synthesis ofRSC advances · 2021Article
- Copper-Catalyzed Annulation-Cyanotrifluoromethylation of 1,6-Enynes Toward 1-Indanones via a Radical Process.Frontiers in chemistry · 2020Article
- A Carbene-Extended ATRA Reaction.Angewandte Chemie (International ed. in English) · 2019Article
- Synthesis of 2-Arylimino-6,7-dihydrobenzo[ACS omega · 2016Article
Corrections and comments
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Authors and funding
7 authors.
Funding
Abstract
A novel three-component carbo-oxygenation of α-diazo carbonyls for flexible synthesis of unprecedented α-aminooxy-β-amino ketones has been established through metal-free C(sp(3))-H functionalization from readily accessible N,N-dimethylanilines and N-hydroxyphthalimide. The reaction pathway involves an in situ-generated phthalimide N-oxyl radical-triggered dediazotization/radical coupling sequence, leading to C-O and C-C bond formation.
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Registered trials
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