ArticleChemistry (Weinheim an der Bergstrasse, Germany)2016
Chemoselective Synthesis of Polysubstituted Pyridines from Heteroaryl Fluorosulfates.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed, 86 citations in OpenAlex.
- Alkenyl Fluorosulfates-Expedient Partners for Palladium-Catalyzed Cross-Coupling Reactions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Electrochemical Single-Carbon Insertion via Distonic Radical Cation Intermediates.Journal of the American Chemical Society · 2025Article
- Pd-, Cu-, and Ni-Catalyzed Reactions: A Comprehensive Review of the Efficient Approaches towards the Synthesis of Antibacterial Molecules.Pharmaceuticals (Basel, Switzerland) · 2024Review
- Aryl fluorosulfates: powerful and versatile partners in cross-coupling reactions.RSC advances · 2023Review
- Synthesis of aliphatic nitriles from cyclobutanone oxime mediated by sulfuryl fluoride (SOBeilstein journal of organic chemistry · 2023Article
- Rapid and column-free syntheses of acyl fluorides and peptides usingChemical science · 2021Article
- Palladium-Catalyzed Cross-Couplings by C-O Bond Activation.Catalysis science & technology · 2020Article
- Continuous flow synthesis of aryl aldehydes by Pd-catalyzed formylation of phenol-derived aryl fluorosulfonates using syngas.RSC advances · 2020Article
- Site-Selective, Modular Diversification of Polyhalogenated Aryl Fluorosulfates (ArOSOAngewandte Chemie (International ed. in English) · 2020Article
- DNA-Encoded Libraries: Aryl Fluorosulfonates as Versatile Electrophiles Enabling Facile On-DNA Suzuki, Sonogashira, and Buchwald Reactions.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2019Article
- Biocompatible SuFEx Click Chemistry: Thionyl Tetrafluoride (SOFAngewandte Chemie (International ed. in English) · 2019Article
- Installation of -SOBeilstein journal of organic chemistry · 2019Article
- SuFEx Chemistry of Thionyl Tetrafluoride (SOFAngewandte Chemie (International ed. in English) · 2018Article
- Multidimensional SuFEx Click Chemistry: Sequential Sulfur(VI) Fluoride Exchange Connections of Diverse Modules Launched From An SOFAngewandte Chemie (International ed. in English) · 2017Article
Corrections and comments
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Authors and funding
6 authors at 3 institutions in 3 countries.
Funding
Abstract
A selection of heteroaryl fluorosulfates were readily synthesized using commercial SO2F2 gas. These substrates are highly efficient coupling partners in the Suzuki reaction. Through judicious selection of Pd catalysts the fluorosulfate functionality is differentiated from bromide and chloride; the order of reactivity being: -Br> -OSO2 F> -Cl. Exploiting this trend allowed the stepwise chemoselective synthesis of a number of polysubstituted pyridines, including the drug Etoricoxib.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.