Evidence map›Paper›PMID 26938461›Full record

ArticleLangmuir : the ACS journal of surfaces and colloids2016

Role of Aromatic Interactions in Temperature-Sensitive Amphiphilic Supramolecular Assemblies.

Oyuntuya Munkhbat, Matteo Garzoni, Krishna R Raghupathi, Giovanni M Pavan, S Thayumanavan

Open access · greenAbstract read
In one paragraph

Article in Langmuir : the ACS journal of surfaces and colloids, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
3.7field-weighted citation impact, top 7% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed, 35 citations in OpenAlex.

  1. Review
  2. Supramolecular Self-Associations of Amphiphilic Dendrons and Their Properties.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021
    Review
  3. Article
  4. Article
  5. Article
  6. Biomacromolecules · 2019
    Article
  7. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors at 2 institutions in 2 countries.

Oyuntuya MunkhbatDepartment of Chemistry, University of Massachusetts , Amherst, Massachusetts 01003, United States.
Matteo GarzoniDepartment of Innovative Technologies, University of Applied Sciences and Arts of Southern Switzerland , Galleria 2, Manno 6928, Switzerland.
Krishna R RaghupathiDepartment of Chemistry, University of Massachusetts , Amherst, Massachusetts 01003, United States.
Giovanni M PavanDepartment of Innovative Technologies, University of Applied Sciences and Arts of Southern Switzerland , Galleria 2, Manno 6928, Switzerland.
S ThayumanavanDepartment of Chemistry, University of Massachusetts , Amherst, Massachusetts 01003, United States.
University of Massachusetts Amherst · USUniversity of Applied Sciences and Arts of Southern Switzerland · CH

Funding

New Amphiphillic Dendrimers for Encapsulation and ReleaseR01GM065255 · NIGMS · UNIVERSITY OF MASSACHUSETTS AMHERST · PI THAYUMANAVAN, SANKARAN · 2003 to 2019
$4.3M
NIGMS NIH HHS GM-065255NIGMS NIH HHS R01 GM065255
6 · The paper itself

Abstract

Aromatic interactions were found to greatly influence the temperature-dependent dynamic behavior within supramolecular assemblies. Using an amphiphilic dendron, we systematically changed the hydrophobic groups introducing increasing levels of aromaticity while keeping the hydrophilic part constant. We show that the supramolecular assemblies become less sensitive to temperature changes when aromatic interactions in the aggregate are increased. Conversely, the absence of aromaticity in the hydrophobic moieties produces temperature-sensitive aggregates. These results show that subtle molecular-level interactions can be utilized to control temperature-sensitive behavior in the nanoscale. These findings open up new design strategies to rationally tune the behavior of stimuli-responsive supramolecular assemblies on multiple spatiotemporal scales.

Indexed as

DendrimersFluorescence Resonance Energy TransferHydrocarbons, AromaticHydrophobic and Hydrophilic InteractionsMolecular Dynamics SimulationParticle SizePerylenePyrenesSurface-Active AgentsTemperatureWaterDendrimersHydrocarbons, AromaticPerylenepyrenePyrenesSurface-Active AgentsWater

Identifiers

PMID26938461
PMCPMC4913888
OpenAlexW2297472655

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.