ArticleAngewandte Chemie (International ed. in English)2016
Transition-Metal-Free Borylation of Allylic and Propargylic Alcohols.
Article in Angewandte Chemie (International ed. in English), 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed.
- Deoxygenative functionalization of alcohols, ethers, and carbonyl compounds by chromium catalysis.Science advances · 2026Article
- Metal-free deoxygenative borylation of pyrazinyl ethersChemical science · 2026Article
- Regioselective Electrochemical Borylation of Oxygenated Allylic Electrophiles: Method Development and Synthetic Applications.ACS central science · 2025Article
- Cu-Catalyzed Chemoselective Borylcupration of Borylated (ACS catalysis · 2025Article
- Computational study on catalyst-free BClRSC advances · 2025Article
- Biomimetic Total Synthesis and Investigation of the Non-Enzymatic Chemistry of Oxazinin A.Angewandte Chemie (International ed. in English) · 2022Article
- Mechanistic study on the reaction of pinB-BMesChemical science · 2021Article
- Tri(boryl)alkanes and Tri(boryl)alkenes: The Versatile Reagents.Molecules (Basel, Switzerland) · 2020Review
- Hexahalodiborate Dianions: A New Family of Binary Boron Halides.Angewandte Chemie (International ed. in English) · 2019Article
- Recent Synthesis Developments of Organoboron Compounds via Metal-Free Catalytic Borylation of Alkynes and Alkenes.Molecules (Basel, Switzerland) · 2018Review
- Reactivity of highly Lewis acidic diborane(4) towards pyridine and isocyanide: formation of boraalkene-pyridine complex andChemical science · 2018Article
- Transition-Metal-Free Borylation of Allylic and Propargylic Alcohols.Angewandte Chemie (International ed. in English) · 2016Article
Corrections and comments
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Authors and funding
4 authors.
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Abstract
The base-catalyzed allylic borylation of tertiary allylic alcohols allows the synthesis of 1,1-disubstituted allyl boronates, in moderate to high yield. The unexpected tandem performance of the Lewis acid-base adduct, [Hbase](+) [MeO-B2 pin2 ](-) favored the formation of 1,2,3-triborylated species from the tertiary allylic alcohols and 1-propargylic cyclohexanol at 90 °C.
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Registered trials
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