ArticleLangmuir : the ACS journal of surfaces and colloids2016
Scanning Electrochemical Microscopy Study of Permeability of a Thiolated Aryl Multilayer and Imaging of Single Nanocubes Anchored to It.
Article in Langmuir : the ACS journal of surfaces and colloids, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
10 citing papers in PubMed.
- High-resolution studies of photo(electro)catalysts by electrochemical scanning probe microscopy.Chemical science · 2026Review
- Review
- Unexpected Inner-Sphere Versus Outer-Sphere Redox in Bilayer Molybdenum Disulfide (MoSChemical & biomedical imaging · 2026Article
- High-Resolution Mapping of Photocatalytic Activity by Diffusion-Based and Tunneling Modes of Photo-Scanning Electrochemical Microscopy.ACS nano · 2025Article
- Nanoelectrochemistry at liquid/liquid interfaces for analytical, biological, and material applications.Chemical communications (Cambridge, England) · 2023Review
- Silver nanoparticles in endodontics: recent developments and applications.Restorative dentistry & endodontics · 2021Review
- Simultaneous Intelligent Imaging of Nanoscale Reactivity and Topography by Scanning Electrochemical Microscopy.Analytical chemistry · 2021Article
- Direct high-resolution mapping of electrocatalytic activity of semi-two-dimensional catalysts with single-edge sensitivity.Proceedings of the National Academy of Sciences of the United States of America · 2019Article
- Characterization of Nanopipet-Supported ITIES Tips for Scanning Electrochemical Microscopy of Single Solid-State Nanopores.Analytical chemistry · 2017Article
- Recent advances in the development and application of nanoelectrodes.The Analyst · 2016Review
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
Electroreduction of diazonium salts is a widely used technique for grafting organic films on various surfaces. In this paper, scanning electrochemical microscopy (SECM) was used for high-resolution characterization of a thiolated aryl multilayer film obtained by electrografting of thiophenol diazonium on highly ordered pyrolytic graphite (HOPG). The blocking properties of the film were evaluated, and the origins of incomplete surface passivation were elucidated by comparing current-distance curves and surface reactivity maps obtained with nanometer- and micrometer-sized tips. In this way, one can distinguish between different pathways of charge transport in the film, e.g., pinhole defects versus rate-limiting charge transfer through the film. Pd nanocubes were anchored to the film by thiol groups and imaged by SECM. The applicability of SECM to in situ visualization of the geometry of non-spherical nanoparticles has been demonstrated.
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What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.