ArticleChemCatChem2016
Improved Efficiency for Partial Oxidation of Methane by Controlled Copper Deposition on Surface-Modified ZSM-5.
Article in ChemCatChem, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Synthesis and characterization of carbon based polymer composites reinforced with MWCNTs and graphite in PVDF matrix.Scientific reports · 2025Article
- Harnessing of Diluted Methane Emissions by Direct Partial Oxidation of Methane to Methanol over Cu/Mordenite.Industrial & engineering chemistry research · 2021Article
- Data science assisted investigation of catalytically active copper hydrate in zeolites for direct oxidation of methane to methanol using HScientific reports · 2021Article
- Improved Efficiency for Partial Oxidation of Methane by Controlled Copper Deposition on Surface-Modified ZSM-5.ChemCatChem · 2016Article
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Authors and funding
4 authors.
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Abstract
The mono(μ-oxo) dicopper cores present in the pores of Cu-ZSM-5 are active for the partial oxidation of methane to methanol. However, copper on the external surface reduces the ratio of active, selective sites to unselective sites. More efficient catalysts are obtained by controlling the copper deposition during synthesis. Herein, the external exchange sites of ZSM-5 samples were passivated by bis(trimethylsilyl) trifluoroacetamide (BSTFA) followed by calcination, promoting selective deposition of intraporous copper during aqueous copper ion exchange. At an optimum level of 1-2 wt % SiO
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