ArticleJournal of the American Chemical Society2016
Scalable, Metal- and Additive-Free, Photoinduced Borylation of Haloarenes and Quaternary Arylammonium Salts.
Article in Journal of the American Chemical Society, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 47 papers.
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Who cites it
47 citing papers in PubMed.
- Verdazyl Radical Organocatalysis Overcomes Chain-Propagation Limitations in Borylation of Arenediazonium Salts.The Journal of organic chemistry · 2026Article
- Metal-free radical borylations: mechanisms, catalytic strategies, and synthetic applications.Chemical science · 2026Review
- Boron in Diet and Medicine: Mechanisms of Delivery and Detection.Pharmaceuticals (Basel, Switzerland) · 2025Review
- Persistent Boryl Radicals as Highly Reducing Photoredox Catalysts for Debrominative Borylations.Journal of the American Chemical Society · 2025Article
- Iodoarene Activation: Take a Leap Forward toward Green and Sustainable Transformations.Chemical reviews · 2025Review
- Article
- Room-Temperature Photochemical Copper-Mediated Fluorination of Aryl Iodides.Organic letters · 2024Article
- Vibration-mediated long-wavelength photolysis of electronegative bonds beyond SCommunications chemistry · 2024Article
- Dinuclear gold-catalyzed divergent dechlorinative radical borylation of gem-dichloroalkanes.Nature communications · 2024Article
- Transition-metal-free synthesis of arylboronates via thermal generation of aryl radicals from triarylbismuthines in air.Beilstein journal of organic chemistry · 2024Article
- Synthetic Advantages of Defluorinative C-F Bond Functionalization.Angewandte Chemie (International ed. in English) · 2023Review
- Unexplored Facet of Pincer Ligands: Super-Reductant Behavior Applied to Transition-Metal-Free Catalysis.JACS Au · 2023Article
- Photocatalytic direct borylation of carboxylic acids.Nature communications · 2022Article
- Light-Driven Hydrodefluorination of Electron-Rich Aryl Fluorides by an Anionic Rhodium-Gallium Photoredox Catalyst.Angewandte Chemie (International ed. in English) · 2022Article
- Solvent Anions Enable Photoinduced Borylation and Phosphonation of Aryl Halides via EDA Complexes.Organic letters · 2022Article
- Merging Electron Deficient Boronic Centers with Electron-Withdrawing Fluorine Substituents Results in Unique Properties of Fluorinated Phenylboronic Compounds.Molecules (Basel, Switzerland) · 2022Review
- Photoinduced metal-free borylation of aryl halides catalysed by anChemical science · 2022Article
- Review
- Technological Innovations in Photochemistry for Organic Synthesis: Flow Chemistry, High-Throughput Experimentation, Scale-up, and Photoelectrochemistry.Chemical reviews · 2022Review
- Direct photo-induced reductive Heck cyclization of indoles for the efficient preparation of polycyclic indolinyl compounds.Chemical science · 2021Article
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Authors and funding
5 authors.
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Abstract
We report herein a simple, metal- and additive-free, photoinduced borylation of haloarenes, including electron-rich fluoroarenes, as well as arylammonium salts directly to boronic acids. This borylation method has a broad scope and functional group tolerance. We show that it can be further extended to boronic esters and carried out on gram scale as well as under flow conditions.
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