ArticleChemphyschem : a European journal of chemical physics and physical chemistry2016
The Role of Resonant Vibrations in Electronic Energy Transfer.
Article in Chemphyschem : a European journal of chemical physics and physical chemistry, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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15 citing papers in PubMed, 61 citations in OpenAlex.
- Vibronic Coherence in a Minimal Pigment-Protein Complex Probed by Two-Dimensional Electronic-Vibrational Spectroscopy.The journal of physical chemistry. B · 2026Article
- Dissipation Pathways in a Photosynthetic Complex.The journal of physical chemistry letters · 2025Article
- Intramolecular charge transfer and the function of vibronic excitons in photosynthetic light harvesting.Photosynthesis research · 2024Review
- Resonant vibrations produce quantum bridge over high-energy states in heterogeneous antenna.Photosynthesis research · 2023Article
- A Comprehensive Approach to Exciton Delocalization and Energy Transfer.Journal of chemical theory and computation · 2022Article
- Exact simulation of pigment-protein complexes unveils vibronic renormalization of electronic parameters in ultrafast spectroscopy.Nature communications · 2022Article
- Hidden vibronic and excitonic structure and vibronic coherence transfer in the bacterial reaction center.Science advances · 2022Article
- Photosynthesis tunes quantum-mechanical mixing of electronic and vibrational states to steer exciton energy transfer.Proceedings of the National Academy of Sciences of the United States of America · 2021Article
- Establishment of theMolecules (Basel, Switzerland) · 2020Article
- Intramolecular vibrations enhance the quantum efficiency of excitonic energy transfer.Photosynthesis research · 2020Article
- Asymmetry in theFrontiers in chemistry · 2020Article
- Quantum Chemical Modeling of the Photoinduced Activity of Multichromophoric Biosystems.Chemical reviews · 2019Review
- Quantum - coherent dynamics in photosynthetic charge separation revealed by wavelet analysis.Scientific reports · 2017Article
- Correlated Fluctuations and Intraband Dynamics of J-Aggregates Revealed by Combination of 2DES Schemes.The journal of physical chemistry letters · 2016Article
- The Role of Resonant Vibrations in Electronic Energy Transfer.Chemphyschem : a European journal of chemical physics and physical chemistry · 2016Article
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Authors and funding
5 authors at 5 institutions in 3 countries.
Funding
Abstract
Nuclear vibrations play a prominent role in the spectroscopy and dynamics of electronic systems. As recent experimental and theoretical studies suggest, this may be even more so when vibrational frequencies are resonant with transitions between the electronic states. Herein, a vibronic multilevel Redfield model is reported for excitonically coupled electronic two-level systems with a few explicitly included vibrational modes and interacting with a phonon bath. With numerical simulations the effects of the quantized vibrations on the dynamics of energy transfer and coherence in a model dimer are illustrated. The resonance between the vibrational frequency and energy gap between the sites leads to a large delocalization of vibronic states, which then results in faster energy transfer and longer-lived mixed coherences.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.