ArticleAngewandte Chemie (International ed. in English)2016
Triazine-Based Sequence-Defined Polymers with Side-Chain Diversity and Backbone-Backbone Interaction Motifs.
Article in Angewandte Chemie (International ed. in English), 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.
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Who cites it
19 citing papers in PubMed.
- Designing Pyridinium-Catalyzed Interfacial Polymerization for High-Performance Acid-Resistant Nanofiltration Membranes.Angewandte Chemie (International ed. in English) · 2026Article
- Synthesis of Porous Polymers by Nucleophilic Substitution Reaction of Polyamines and Monochlorotriazinyl-β-Cyclodextrin and Application to Dye Adsorption.Materials (Basel, Switzerland) · 2025Article
- Efficient automated solid-phase synthesis of recognition-encoded melamine oligomers.Chemical science · 2024Article
- Selective Duplex Formation in Mixed Sequence Libraries of Synthetic Polymers.Journal of the American Chemical Society · 2024Article
- Discrete Oligocarbamates Exhibit Sequence-Dependent Fluorescence Emission and Quenching.ACS polymers Au · 2023Article
- Synthesis and In Vitro Comparison of DOTA, NODAGA and 15-5 Macrocycles as Chelators for theMolecules (Basel, Switzerland) · 2022Article
- Dynamic Bonds: Adaptable Timescales for Responsive Materials.Angewandte Chemie (International ed. in English) · 2022Review
- Article
- High-Fidelity Sequence-Selective Duplex Formation by Recognition-Encoded Melamine Oligomers.Journal of the American Chemical Society · 2021Article
- Dual sequence definition increases the data storage capacity of sequence-defined macromolecules.Communications chemistry · 2020Article
- Amphiphilic Triazine Polymer Derivatives as Antibacterial And Anti-atopic Agents in Mice Model.Scientific reports · 2019Article
- Sequence-Controlled Polymers Through Entropy-Driven Ring-Opening Metathesis Polymerization: Theory, Molecular Weight Control, and Monomer Design.Journal of the American Chemical Society · 2019Article
- A versatile strategy for the synthesis of sequence-defined peptoids with side-chain and backbone diversityChemical science · 2019Article
- Sequence-definition in stiff conjugated oligomers.Scientific reports · 2018Article
- Multifunctional sequence-defined macromolecules for chemical data storage.Nature communications · 2018Article
- Metal-organic and covalent organic frameworks as single-site catalysts.Chemical Society reviews · 2017Review
- Coding and decoding libraries of sequence-defined functional copolymers synthesized via photoligation.Nature communications · 2016Article
- Sequence-Defined Oligomers from Hydroxyproline Building Blocks for Parallel Synthesis Applications.Angewandte Chemie (International ed. in English) · 2016Article
- Triazine-Based Sequence-Defined Polymers with Side-Chain Diversity and Backbone-Backbone Interaction Motifs.Angewandte Chemie (International ed. in English) · 2016Article
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3 authors.
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Abstract
Sequence control in polymers, well-known in nature, encodes structure and functionality. Here we introduce a new architecture, based on the nucleophilic aromatic substitution chemistry of cyanuric chloride, that creates a new class of sequence-defined polymers dubbed TZPs. Proof of concept is demonstrated with two synthesized hexamers, having neutral and ionizable side chains. Molecular dynamics simulations show backbone-backbone interactions, including H-bonding motifs and pi-pi interactions. This architecture is arguably biomimetic while differing from sequence-defined polymers having peptide bonds. The synthetic methodology supports the structural diversity of side chains known in peptides, as well as backbone-backbone hydrogen-bonding motifs, and will thus enable new macromolecules and materials with useful functions.
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