ArticleChemical communications (Cambridge, England)2016
Catalytic insertion of aldehydes into dihalonitroacetophenones via sequential bond scission-aldol reaction-acyl transfer.
Article in Chemical communications (Cambridge, England), 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Enantioseparation and racemization of 3-fluorooxindoles.Chirality · 2023Article
- Selective CspSynthesis · 2022Article
- Article
- Palladium and Nickel Catalyzed Suzuki Cross-Coupling with Alkyl Fluorides.Organic letters · 2021Article
- Organocatalytic Stereoselective Synthesis of Fluorinated 3,3'-Linked Bisoxindoles.The Journal of organic chemistry · 2018Article
- Article
- Organocatalytic Insertion of Isatins into Aryl Difluoronitromethyl Ketones.The Journal of organic chemistry · 2017Article
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Authors and funding
2 authors.
Funding
Abstract
A catalytic process that provides dihalogenated nitro alcohols in up to 99% yield and with 100% atom economy is described. In situ cleavage of dihalonitroacetophenones affords nitronates that undergo Lewis acid catalyzed addition to aldehydes. Final benzoylation renders the sequence irreversible and regenerates the bond scission and acyl transfer agent.
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