ArticleAngewandte Chemie (International ed. in English)2016
Palladium-Catalyzed C-H Arylation of α,β-Unsaturated Imines: Catalyst-Controlled Synthesis of Enamine and Allylic Amine Derivatives.
Article in Angewandte Chemie (International ed. in English), 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
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Who cites it
21 citing papers in PubMed.
- Palladium-catalyzed benzylic C(spChemical science · 2021Article
- Transition-metal-free allylation of 2-azaallyls with allyl ethers through polar and radical mechanisms.Nature communications · 2021Article
- Design and Synthesis of Fluorescent 1,3-Diaryl-β-carbolines and 1,3-Diaryl-3,4-dihydro-β-carbolines.ACS omega · 2021Article
- Nickel-catalyzed enantioselective vinylation of aryl 2-azaallyl anions.Chemical science · 2021Article
- 10-Phenyl-10IUCrData · 2020Article
- 2-Azadienes as Enamine Umpolung Synthons for the Preparation of Chiral Amines.Synlett : accounts and rapid communications in synthetic organic chemistry · 2019Article
- Regio- and Enantioselective (Het)arylation of β-Alkenyl Pyrroline to α-Aryl-β-alkenyl Pyrrolidines.ACS omega · 2019Article
- Intramolecular Umpolung Synthesis of Exocyclic β-Amino Alcohols through Decarboxylative Amination.ACS omega · 2018Article
- Sulfenate anions as organocatalysts for benzylic chloromethyl coupling polymerization via C=C bond formation.Nature communications · 2018Article
- Palladium-Catalyzed Triarylation of spAdvanced synthesis & catalysis · 2018Article
- 2-Azadienes as Reagents for Preparing Chiral Amines: Synthesis of 1,2-Amino Tertiary Alcohols by Cu-Catalyzed Enantioselective Reductive Couplings with Ketones.Journal of the American Chemical Society · 2018Article
- Biointeractions of Herbicide Atrazine with Human Serum Albumin: UV-Vis, Fluorescence and Circular Dichroism Approaches.International journal of environmental research and public health · 2018Article
- Transition-Metal-Free Radical C(spJournal of the American Chemical Society · 2017Article
- Transition-metal-free chemo- and regioselective vinylation of azaallyls.Nature chemistry · 2017Article
- Arylation of Azaarylmethylamines with Aryl Chlorides and a NiBrAdvanced synthesis & catalysis · 2017Article
- Synthesis of Diarylated 4-Pyridylmethyl Ethers via Palladium-Catalyzed Cross-Coupling Reactions.Advanced synthesis & catalysis · 2017Article
- Palladium-catalysed synthesis of triaryl(heteroaryl)methanes.Nature communications · 2017Article
- Tandem C(spAdvanced synthesis & catalysis · 2016Article
- Palladium-Catalyzed α-Arylation of Methyl Sulfonamides with Aryl Chlorides.Advanced synthesis & catalysis · 2016Article
- Umpolung Synthesis of Diarylmethylamines via Palladium-Catalyzed Arylation ofAdvanced synthesis & catalysis · 2016Article
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6 authors.
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Abstract
A unique chemo- and regioselective α- and γ-arylation of palladium azapentadienyl intermediates is presented. Two distinct catalysts and sets of conditions successfully controlled the regioselectivity of the arylation. These methods provide the first umpolung C-H functionalization of azapentadienyl palladium intermediates and enable the divergent synthesis of allylic amine and enamine derivatives, which are of significant interest in the pharmaceutical industry.
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