Evidence map›Paper›PMID 26832822›Full record

ArticleScientific reports2016

An Unexpected Controlled New Oxidant: SO4(·-).

Cui-Bing Bai, Nai-Xing Wang, Xing-Wang Lan, Yan-Jing Wang, Yalan Xing, Jia-Long Wen, Xue-Wang Gao, Wei Zhang

Open access · goldAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Scientific reports, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
1.1field-weighted citation impact, top 18% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed, 11 citations in OpenAlex.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors at 3 institutions in 2 countries.

Cui-Bing BaiTechnical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.
Nai-Xing WangTechnical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.
Xing-Wang LanTechnical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.
Yan-Jing WangTechnical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.
Yalan XingDepartment of Chemistry, William Paterson University of New Jersey, 300 Pompton Road, Wayne, New Jersey 07470, United States.
Jia-Long WenTechnical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.
Xue-Wang GaoTechnical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.
Wei ZhangTechnical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.
Chinese Academy of Sciences · CNTechnical Institute of Physics and Chemistry · CNWilliam Paterson University · US

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

A controlled new oxidant sulfate radical anion (SO4(·-)) was found and it can be easily prepared by mixing Na2S2O4 and TBHP with stirring. In this new metal-free oxidation system (Na2S2O4/TBHP), SO4(·-) can be used as a controllable oxidant to oxidize various aromatic alcohols to the corresponding aldehydes in good yields without any acid formation at room temperature. SO4(·-) was determined by a DMPO (5,5-dimethyl-1-pyrroline-N-oxide) spin-trapping EPR method at room temperature on a Bruker E500 spectrometer and the results suggested that SO4(·-) was generated in this transformation.

Identifiers

PMID26832822
PMCPMC4735593
OpenAlexW2465387425

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.