ArticleOrganic letters2016
Visible Light Photoredox Cross-Coupling of Acyl Chlorides with Potassium Alkoxymethyltrifluoroborates: Synthesis of α-Alkoxyketones.
Article in Organic letters, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 26 papers.
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Who cites it
26 citing papers in PubMed, 111 citations in OpenAlex.
- Photoredox-Catalyzed Radical-Radical Coupling of Potassium Trifluoroborates with Acyl Azoliums.Synlett : accounts and rapid communications in synthetic organic chemistry · 2023Article
- One step synthesis of unsymmetrical 1,3-disubstituted BCP ketonesChemical science · 2022Article
- Combined Photoredox and Carbene Catalysis for the Synthesis of γ-Aryloxy Ketones.Advanced synthesis & catalysis · 2022Article
- Photo-Induced Ruthenium-Catalyzed C-H Benzylations and Allylations at Room Temperature.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Benzylic C(spChemical science · 2021Article
- Stereoinduction in Metallaphotoredox Catalysis.Angewandte Chemie (International ed. in English) · 2021Review
- Stereochemistry of Transition Metal Complexes Controlled by the Metallo-Anomeric Effect.Journal of the American Chemical Society · 2020Article
- Recent advances in photoredox and nickel dual-catalyzed cascade reactions: pushing the boundaries of complexity.Chemical science · 2020Review
- Photochemical Asymmetric Nickel-Catalyzed Acyl Cross-Coupling.Angewandte Chemie (International ed. in English) · 2019Article
- Alkyl Carbon-Carbon Bond Formation by Nickel/Photoredox Cross-Coupling.Angewandte Chemie (International ed. in English) · 2019Review
- Photoredox/Nickel-Catalyzed Single-Electron Tsuji-Trost Reaction: Development and Mechanistic Insights.Angewandte Chemie (International ed. in English) · 2018Article
- Direct C-C Bond Formation from Alkanes Using Ni-Photoredox Catalysis.Journal of the American Chemical Society · 2018Article
- Radical-Based C-C Bond-Forming Processes Enabled by the Photoexcitation of 4-Alkyl-1,4-dihydropyridines.Angewandte Chemie (International ed. in English) · 2017Article
- Nickel/Photoredox-Catalyzed Amidation via Alkylsilicates and Isocyanates.ACS catalysis · 2017Article
- Direct Conversion of Carboxylic Acids to Alkyl Ketones.Organic letters · 2017Article
- Synergistic Visible-Light Photoredox/Nickel-Catalyzed Synthesis of Aliphatic Ketones via N-C Cleavage of Imides.Organic letters · 2017Article
- Metal-free C-H alkylation of heteroarenes with alkyltrifluoroborates: a general protocol for 1°, 2° and 3° alkylation.Chemical science · 2017Article
- Photoredox-Mediated Routes to Radicals: The Value of Catalytic Radical Generation in Synthetic Methods Development.ACS catalysis · 2017Review
- Preparation of visible-light-activated metal complexes and their use in photoredox/nickel dual catalysis.Nature protocols · 2017Article
- Direct α-Arylation/Heteroarylation of 2-Trifluoroboratochromanones via Photoredox/Nickel Dual Catalysis.Organic letters · 2017Article
Corrections and comments
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Authors and funding
3 authors at 1 institution in 1 country.
Funding
Abstract
A visible-light, single-electron-transfer (SET), photoredox cross-coupling for the synthesis of α-alkoxyketones has been developed. In this method, various aliphatic and aromatic acyl chlorides were successfully coupled with structurally diverse potassium alkoxymethyltrifluoroborates, producing the corresponding α-alkoxyketones with high yields. In this operationally simple and mild cross-coupling protocol, the desired ketones are obtained in one step from bench stable starting materials by a bond connection that is unique to both alkylboron chemistry and photoredox/Ni catalysis.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.