ArticleAngewandte Chemie (International ed. in English)2016
Hydrogen Bonds Dictate the Coordination Geometry of Copper: Characterization of a Square-Planar Copper(I) Complex.
Article in Angewandte Chemie (International ed. in English), 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 24 papers.
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Who cites it
24 citing papers in PubMed.
- Unlocking Distinct Excited States of a Nickel(II) Complex Without Modulating the Primary Coordination Sphere.JACS Au · 2026Article
- Protein-Enforced Ligand Environments Reshape Classical Coordination Preferences in Copper Polypyridyl Complexes.Journal of the American Chemical Society · 2026Article
- Taxonomy of Chemical Bondings: Opportunities and Challenges.Angewandte Chemie (International ed. in English) · 2025Article
- Crystal Lattice-Induced Stress modulates Photoinduced Jahn-Teller Distortion Dynamics.ACS physical chemistry Au · 2024Article
- Bis(2,6-pyrazolyl)pyridines as a New Scaffold for Coordination Polymers.Molecules (Basel, Switzerland) · 2023Article
- Synthesis and Photophysical Properties of α-(Molecules (Basel, Switzerland) · 2022Article
- Manipulating electron transfer - the influence of substituents on novel copper guanidine quinolinyl complexes.Chemical science · 2022Article
- The underappreciated influence of ancillary halide on metal-ligand proton tautomerism.Chemical science · 2022Article
- Influence of the spatial distribution of copper sites on the selectivity of the oxygen reduction reaction.Dalton transactions (Cambridge, England : 2003) · 2022Article
- Construction of Two Stable Co(II)-Based Hydrogen-Bonded Organic Frameworks as a Luminescent Probe for Recognition of FeMolecules (Basel, Switzerland) · 2021Article
- Encapsulation of tricopper cluster in a synthetic cryptand enables facile redox processes from CuChemical science · 2020Article
- Influence of Ligand Denticity and Flexibility on the Molecular Copper Mediated Oxygen Reduction Reaction.Inorganic chemistry · 2020Article
- Revisiting dithiadiaza macrocyclic chelators for copper-64 PET imaging.Dalton transactions (Cambridge, England : 2003) · 2020Article
- Examining the Generality of Metal-Ligand Cooperativity Across a Series of First-Row Transition Metals: Capture, Bond Activation, and Stabilization.Inorganic chemistry · 2020Article
- Reductively Stable Hydrogen-Bonding Ligands Featuring Appended CFJournal of the American Chemical Society · 2020Article
- Rotaxane PtChemical science · 2020Article
- Low Reorganization Energy for Electron Self-Exchange by a Formally Copper(III,II) Redox Couple.Inorganic chemistry · 2019Article
- Early Metal Di(pyridyl) Pyrrolide Complexes with Second Coordination Sphere Arene-π Interactions: Ligand Binding and Ethylene Polymerization.ACS omega · 2019Article
- Tuning ligand field strength with pendent Lewis acids: access to high spin iron hydrides.Chemical science · 2019Article
- Hydrogen Bonds Dictate OJournal of the American Chemical Society · 2018Article
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2 authors.
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Abstract
6,6''-Bis(2,4,6-trimethylanilido)terpyridine (H2Tpy(NMes)) was prepared as a rigid, tridentate pincer ligand containing pendent anilines as hydrogen bond donor groups in the secondary coordination sphere. The coordination geometry of (H2 Tpy(NMes))copper(I)-halide (Cl, Br and I) complexes is dictated by the strength of the NH-halide hydrogen bond. The Cu(I)Cl and Cu(II)Cl complexes are nearly isostructural, the former presenting a highly unusual square-planar geometry about Cu(I) . The geometric constraints provided by secondary interactions are reminiscent of blue copper proteins where a constrained geometry, or entatic state, allows for extremely rapid Cu(I)/Cu(II) electron-transfer self-exchange rates. Cu(H2 Tpy(NMes))Cl shows similar fast electron transfer (≈10(5) m(-1) s(-1)) which is the same order of magnitude as biological systems.
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