ReviewChemical Society reviews2016
Copper mediated carbometalation reactions.
Review in Chemical Society reviews, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 30 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
30 citing papers in PubMed.
- Routes to Cyclobutadiene and Cycloallyl Pt(II) Complexes: Dicationic Bis(Alkyne) Species as Intermediates.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Redox-Divergent Reactivity of a Gallium(I) Ambiphile toward an Allene, a Diyne, and Ph3PCN2.Inorganic chemistry · 2026Article
- Engineering an Artificial Myxopyronin Derivative with Enhanced Metabolic Stability via Mutasynthesis.JACS Au · 2025Article
- Dearomative Cyclization of Ynamides toward the Formation of Fused Diazabicycles.Organic letters · 2025Article
- Axially chiral α-boryl-homoallenyl boronic esters as versatile toolbox for accessing centrally and axially chiral molecules.Nature communications · 2024Article
- Redox Reorganization: Aluminium Promoted 1,5-Hydride Shifts Allow the Controlled Synthesis of Multisubstituted Cyclohexenes.Angewandte Chemie (International ed. in English) · 2023Article
- Copper-Catalyzed Regiodivergent Internal Allylic Alkylations.Angewandte Chemie (International ed. in English) · 2023Article
- Gold-catalyzed four-component multifunctionalization of alkynes.Nature communications · 2023Article
- Cobalt-catalyzed radical-mediated carbon-carbon scissionChemical science · 2023Article
- AChemical science · 2023Article
- Rapid and Modular Access to Vinyl Cyclopropanes Enabled by Air-stable Palladium(I) Dimer Catalysis.Angewandte Chemie (International ed. in English) · 2023Article
- Schlenk's Legacy-Methyllithium Put under Close Scrutiny.Angewandte Chemie (International ed. in English) · 2023Article
- Article
- Preparation of Chiral Enantioenriched Densely Substituted Cyclopropyl Azoles, Amines, and Ethers via Formal SMolecules (Basel, Switzerland) · 2022Article
- Regio- and Diastereoselective Carbometalation Reaction of Cyclopropenes.Accounts of chemical research · 2022Article
- Stereoselective Synthesis of Polysubstituted Spiropentanes.Journal of the American Chemical Society · 2022Article
- Organocopper(ii) complexes: new catalysts for carbon-carbon bond formationChemical science · 2022Article
- Borylated Cyclopropanes as Spring-Loaded Entities: Access to Vicinal Tertiary and Quaternary Carbon Stereocenters in Acyclic Systems.Journal of the American Chemical Society · 2022Article
- Direct Stereodivergent Olefination of Carbonyl Compounds with Sulfur Ylides.Journal of the American Chemical Society · 2022Article
- Copper-Catalyzed Enantioselective Hydrosilylation of gem-Difluorocyclopropenes Leading to a Stereochemical Study of the Silylated gem-Difluorocyclopropanes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
2 authors.
Funding
Abstract
Since the first discovery of carbocupration of alkynes in the 1970s a tremendous amount of research has been carried out in this field. The exceptionally high selectivities obtained attribute to the great synthetic value of carbocupration reactions. This tutorial review will present the most important features of carbocupration of alkynes and highlight the most relevant reviews. Then a comprehensive review of copper mediated carbometalation of cyclopropenes will follow. The latter method has received much attention over the last decade as it allows the highly selective construction of poly-substituted cyclopropanes which can be transformed into acyclic derivatives bearing one or multiple tertiary or quaternary carbon stereocenters.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.